Materials that can produce electricity are at the core of piezoelectric research and the vision of self-powering machines and devices. Nanotechnology researchers are even pursuing nanopiezotronics devices that have the potential of converting biological mechanical energy, acoustic/ultrasonic vibration energy, and biofluid hydraulic energy into electricity, demonstrating a new pathway for self-powering of wireless nanodevices and nanosystems. In addition to miniaturizing piezoelectric devices down to the nanoscale, nanotechnology is also contributing to making next-generation devices more effective. Piezoelectric ceramics for instance generate electrical charge or voltage when they experience stress/strain, and thus are highly efficient at converting mechanical energy into electrical energy. However, ceramics are rigid, which greatly limits the applicability of the energy harvesting. Researchers have now demonstrated that high performance piezoelectric ceramics can be transferred in a scalable process onto rubber or plastic, rendering them flexible without any sacrifice in energy conversion efficiency.
Scientists have great expectations that nanotechnologies will bring them closer to the goal of creating computer systems that can simulate and emulate the brain's abilities for sensation, perception, action, interaction and cognition while rivaling its low power consumption and compact size. DARPA for instance has a program called SyNAPSE that is trying to develop electronic neuromorphic machine technology that scales to biological levels. Started in late 2008 and funded with $4.9 million, the goal of the initial phase of the SyNAPSE project is to 'develop nanometer scale electronic synaptic components capable of adapting the connection strength between two neurons in a manner analogous to that seen in biological systems, as well as, simulate the utility of these synaptic components in core microcircuits that support the overall system architecture.' Independent from this military-inspired research, nanotechnology researchers in France have developed a hybrid nanoparticle-organic transistor that can mimic the main functionalities of a synapse. This organic transistor, based on pentacene and gold nanoparticles and termed NOMFET (Nanoparticle Organic Memory Field-Effect Transistor), has opened the way to new generations of neuro-inspired computers, capable of responding in a manner similar to the nervous system.
The key for most visionary electronic applications will be printability, i.e. that the circuits can be applied to any material, and flexibility, i.e. that they can adhere to any shape or form - even body parts. Imagine an ultrathin film of electronic circuits attached to internal organs like your heart to monitor vital functions. All existing forms of electronics are built on the two-dimensional, planar surfaces of either semiconductor wafers or plates of glass. Mechanically flexible circuits based on organic semiconductors are beginning to emerge into commercial applications, but they can only be wrapped onto the surfaces of cones or cylinders - they cannot conform to spheres or any other type of surface that exhibits non-Gaussian curvature. Applications that demand conformal integration, e.g. structural or personal health monitors, advanced surgical devices, or systems that use ergonomic or bio-inspired layouts, etc., require circuit technologies in curvilinear layouts.
Chip structures already have reached nanoscale dimensions but as they continue to shrink below the 20 nanometer mark, ever more complex challenges arise and scaling appears not to be economically feasible any more. And below 10 nm, the fundamental physical limits of CMOS technology will be reached.
One promising material that could enable the chip industry to move beyond the current CMOS technology is graphene, a monolayer sheet of carbon. Notwithstanding the intense research interest, large scale production of single layer graphene remains a significant challenge. Researchers at Cornell University have now reported a new technique for producing large scale single layer graphene sheets and fabricating transistor arrays with uniform electrical properties directly on the device substrate.
Graphene is an impressive condensed matter system that, to all appearances, never ceases to impress and challenge our entrenched intuitions regarding solid state systems. But graphene is a highly atypical electronic system in that it consists of nothing but a surface. Researchers at Boston University have found that local deformations in a graphene sheet can strongly influence electron flow across the system, causing suppression of conductance at low densities, and making electrons behave as if they were living in a nanoribbon or quantum dot. All this without cutting the graphene sheet, which opens the prospect towards a reversible and controllable transport gap in monolayer graphene via strain engineering.
Imagine this: Chip-based credit cards and other smart cards on paper; intelligent sensors and electronics on doctors' surgical gloves; health monitors printed on T-shirts; diagnostic devices embedded in your baby's diapers; human machine interfaces on workers' leather gloves. These are just some of the systems that researchers envision today and that will become reality tomorrow thanks to research teams like John Rogers' group at the University of Illinois. Nanotechnology-enabled electronics of the future will be invisible, i.e. transparent, or flexible, or both. One of the areas Rogers' group focus on is creating materials and processes that will allow high-performance electronics that are flexible and stretchable. The group has now demonstrated examples of CMOS circuits on paper, fabric, leather and vinyl.
DNA origami, tiny shapes and patterns self-assembled from DNA, have been heralded as a potential breakthrough for the creation of nanoscale circuits and devices. One roadblock to their use has been that they are made in solution, and they stick randomly to surfaces - like a deck of playing cards thrown onto a floor. Random arrangements of DNA origami are not very useful; if they carry electronic circuits for example, they are difficult to find and 'wire-up' into larger circuits. A collaboration between Caltech and IBM research Almaden has found a way to position and orient DNA origami on surfaces by creating sticky patches in the shape of origami - as a demonstration they positioned and aligned triangular DNA origami on triangular sticky patches. This success knocks down one of the major roadblocks for the use of DNA origami in computer nanotechnology.
The degree of mobility of a semiconductor, i.e. how well it conducts, is crucial to the effectiveness of nanoelectronic devices. Mobility determines the carrier velocity, and hence switching speed, in FETs. Researchers have determined that the theoretical mobility of an individual single-walled carbon nanotube is about 1000 times higher than any other known semiconductor. However, practical applications would require massive manufacturing of large scale nanoelectronic devices. Despite progress being made with integrating individual nanotubes in lab environments, many of today's nanomanufacturing techniques for nanoelectronic devices rely on the use of 'carbon nanotube network films' comprised of multiple carbon nanotubes. The major problem here is that the electronic properties of CNT network films are usually very poor. Researchers in South Korea have now developed a powerful strategy to solve these fundamental problems simply by controlling the connectivity of nanotube/nanowire networks.