Glues adhere to solid materials via a multitude of fundamental physical or chemical interactions. Either chemical reaction times or solvent evaporation rates determine the point in time, when this interaction sets in and fixes the object to be glued. Electric potential has been used to attract polymers continuously to an electrode surface and to toggle molecules between states for a molecular switch. If you wanted to create electric glue, you would need to be able to control the interaction of a polymer and an electrode surface reversibly, thus creating a nanoscale system with electrochemically controlled adhesion. A research team now describes how Coulomb forces between polymers and surfaces may be measured, controlled, and manipulated.
Ink-jet printing of metal nanoparticles for conductive metal patterns has attracted great interest as an alternative to expensive fabrication techniques like vapor deposition. The bulk of the research in this area focuses on printing metal nanoparticle suspensions (metallic ink) for metallization. Printing conductive features by metallic nanoparticle inks must be followed by an additional step of sintering, usually achieved by heating to elevated temperatures. In this step, the nanoparticles composing the pattern will coalesce to form a continuous electrical contact. In new work, researchers have now demonstrated a new conductive ink that won't require a post printing sintering step. It is achieved by the addition of a latent sintering agent that gets into action after the printing step. Once the solvent evaporates, the sintering agent concentration increases, leading to the spontaneous sintering of the nanoparticles.
Printed electronics is one of the most important new enabling technologies. It will have a major impact on most business activities from publishing and security printing to healthcare, automotive, military and consumer packaged goods sectors. With recent advances, power and energy storage can be integrated into the printing process, making their potential applications even more ubiquitous. Currently, though, the more complex printed components that require a combination of different class of devices, still experience drawbacks in performance, cost, and large-scale manufacturability. Researchers have now succeeded in fabricating a multi-component sensor array by simple printing techniques - all components (polymer sensor array, organic transistors, electrochromic display) are integrated on the same flexible substrate.
In order to find replacement materials for ITO, scientists have been working with carbon nanotubes, graphene, and other nanoscale materials such as nanowires. While many of these approaches work fine in the lab, upscaleability usually has been an issue. Researchers at Empa, the Swiss Federal Laboratories for Material Science and Technology, have now demonstrated another solution: they presented a transparent and flexible electrode based on a precision fabric with metal and polymer fibers woven into a mesh. The team demonstrated organic solar cells fabricated on their flexible precision fabrics as well as on conventional glass/ITO substrates and found very similar performance characteristics.
The power conversion efficiency of solar cells made of conjugated polymer/nanorod nanocomposites can be maximized when the nanocomposites are aligned perpendicularly between two electrodes for effective exciton dissociation and transport. To realize this, external fields can be applied to induce the self-assembly/alignment. The challenge is how to assemble them over a large scale - current self-assembly studies of cadmium selenide nanorods in literature are limited to only a micrometer scale. New design approaches are therefore needed to solve this problem. Due to their intrinsic structural anisotropy, nanorods possess many unique properties that make them potentially better nanocrystals than quantum dots for photovoltaics and biomedical applications.
Photonic crystals are used to guide and localize light for all-optical processing of signals/information; to engineer dispersion and slow light; to harvest light (collect and redirect); and thresholdless lasing, that can be engineered by setting spectral ranges where light can be emitted. so far, there have been no demonstrations of full photonic bandgap at visible wavelengths - i.e., that at a certain visible range (between 400 nm to 780 nm) determined by the 3D photonic crystal structure, the light is rejected (reflected) at all angles of incidence. Researchers have now used a 3D nano-sculpturing process to fabricate 3D photonic crystal. The great potential of these 3D photonic crystal lies in the possibility to control light on a sub-wavelength scale.
Although organic semiconductor materials cannot yet be packed as densely as state-of-the-art silicon chips, they require less power, cost less and do things silicon devices cannot: bend and fold, for example. Once perfected, organic semiconductors will permit the construction of low-cost, spray-on solar cells and even spray-on video displays. Notwithstanding tremendous progress in the area of organic electronics, several major challenges still exist. To address these challenges, researchers have combined organic electronics with nanoelectronics and developed the first 2D crystal of organic semiconductors on the millimeter scale, the thickness of which is only a single molecular layer, but with perfect long-ranged crystalline order.
Currently, the most common methods for sizing nanoparticles extract data from bulk measurements. These techniques are inherently averaging and so are unable to effectively resolve mixtures of different-sized particles. While individual nanoparticles can be sized using electron microscopy, this approach is time-consuming and of little utility in assembling significant population statistics. Researchers have now developed a microfluidic device for the all-electronic analysis of complex suspensions of nanoparticles in fluid. This device is capable of detecting and sizing individual and unlabeled particles as small as a few tens of nanometers in diameter at rates estimated to exceed 100,000 particles per second.