Colloidal materials have been playing a major role in many research fields such as chemistry, materials science, condensed matter physics, applied optics, fluid dynamics, and biology. Most of these studies require the use of monodisperse colloidal particles with uniformity in shape, size, composition, structure and surface properties. Both our current understanding of various physical phenomena and our capability to fabricate new functional materials have been considerably enriched by the development of synthetic strategies that are capable of generating copious quantities of colloidal entities of good size uniformity. Nevertheless, most of the available monodisperse colloidal materials are spherical because this represents a thermodynamically favorable state in terms of surface energy. This strongly limits the number of new structures which can be engineered by using these colloids as building blocks. A novel synthetic route can now produce a full set of new non-spherical, binary colloids with regular morphology in a high yield.
The thing with technology is that the science behind it isn't good or bad but the way it is used could make all the difference. There are plenty of examples throughout history. Military nanotechnology is a good present day example. And we don't even need to talk about the weird, far-out stuff like nanobots and the Casimir force. Take explosives. While on one side there is research going on to improve high explosives through nanoscale structuring, other research teams are putting a lot of effort into detecting ever smaller trace amounts of explosives and building the ultimate nanoscale bomb dog. A recent example has been demonstrated by scientists in China, who obtained organic super-nanostructures via a simple solution process, and, for the first time, demonstrated that such structures can be applied as chemosensors to detect explosives.
Civilization as we know it would, literally, fall apart without techniques to join materials together. With its historic development tracing back to the Bronze Age, welding has been one of the key technologies that serves modern industry in broad areas such as construction, manufacturing, and engineering. As we have reported in a previous Nanotechnology Spotlight, this Bronze Age technique could prove very useful in building complex nanostructures. Researchers at the University of Sheffield in the UK have now demonstrated the ability to reliably weld individual nanowires and nanoobjects into complex geometries with controllable junctions. This represents a significant breakthrough for the current and future bottom-up localized assembly, integration, and repair of micro- and nanodevices.
The performance of devices like organic light emitting diodes (OLEDs), flexible solar cells, or plastic electronics is sensitive to moisture because water and oxygen molecules seep past the protective plastic layer over time and degrade the organic materials which form the core of these products. To protect these sensitive devices, barrier technologies have been developed that protect them from environmental degradation. State-of-the-art barrier materials employ metal oxide thin films, commonly from aluminum or silicon oxides, which provide excellent protection from atmospheric oxygen and water, but still suffer from problems. A new study demonstrates a nanocomposite material that can initiate self-healing upon the influx of water through pores and cracks by delivering titanium dioxide nanoparticles to the defective site, which ultimately slows the rate of moisture diffusion to the reactive electronic device.
Scientists are intensely researching how animals like spiders and geckos generate the high adhesion force that allows them to cling to walls and walk on ceilings, feet over their head. While this research so far has focused on novel materials like carbon nanotubes to replicate spider feet and gecko toes, a key challenge for materials engineers is the scaling up of such materials from small animals to, say, spiderman gloves that support a fully grown human. Complementing the ongoing gecko biomimetic materials research, Nicola M. Pugno, an Associate Professor of Structural Mechanics at the Politecnico di Torino in Italy, has developed what he termed Adhesive Optimization Laws.
Advances in micro- and nanoscale engineering have led to various mobile devices that either can move on solids or swim in fluids. Researchers are applying various strategies to designing nanoscale propulsion systems by either using or copying biological systems such as the flagellar motors of bacteria or by employing various chemical reactions. Many of these approaches are fairly complex and not necessarily suited for large-scale deployment in practical applications. Scientists have theorized about simpler designs for mechanical swimmers that avoid the complexities of biological mechanisms and use very few degrees of freedom.
Researchers in Spain have now demonstrated the experimental realization of a simple device made by microscopic colloidal particles which can be externally controlled and propelled at low Reynolds number condition, i.e. when the viscosity of the fluid dominates over the inertia of the object. This is the same condition that governs the motion of bacteria such as E. Coli or other micro- or nanoscale objects that move in a fluid.
Nanotechnology researchers are actively working on the beginnings of various nanorobotic systems that one day could lead to automated, assembly-line type nanofabrication processes. Last year we reported on a nanogripper, a kind of a robotic 'hand' some ten thousand times smaller than a human hand. This 'pick-and-place' device used a silicon gripper which was controlled by a nanorobotic arm and was capable of picking up a carbon nanofiber and fix it onto the tip of an atomic force microscope cantilever. One of the problems that is vexing researchers is that the nanoscale miniaturization of these grippers comes at the cost of reduced strength - the smaller the gripper, the weaker it becomes. Therefore what is needed is a gripper design that is strong enough yet sufficient flexible and small to handle tough materials like carbon nanotubes.
Shrinking device size to nanometer dimensions presents many fascinating opportunities such as manipulating nano objects with nanotools, measuring mass in attogram ranges, sensing forces at femtonewton scales, and inducing gigahertz motion, among other new possibilities waiting to be discovered. The two principal components common to most electromechanical systems irrespective of scale are a mechanical element and transducers. The mechanical element either deflects or vibrates in response to an applied force. Depending on their type, the mechanical elements can be used to sense static or time-varying forces. The transducers in microelectromechanical systems (MEMS) and nanoelectromechanical systems (NEMS) convert mechanical energy into electrical or optical signals and vice versa. A Spanish team has now demonstrated an ultrasensitive carbon nanotube based mass sensor in which they measured chromium atoms with a mass resolution of only 1.4 zeptograms.