Counter intuitive to our idea of 'perfection equals best performance', researchers have shown that defects in nanocarbons could provide a breakthrough for increasing the quantum capacitance. By subjecting graphene layers to a reactive-ion etching process, the team has poked holes into graphene to create holey graphene, which can change the microscopic distribution of electrons and thereby increase the quantum capacitance of graphene by at least fourfold.
From a 3D printing perspective, graphene has been previously incorporated into 3D printed materials, but most of these constructs comprise no greater than about 20 volume % of the total solid of the composite, resulting in electrical properties that are significantly less than what has been achieced in new work. Here, researchers show that high volume fraction graphene composite constructs can be formed from an easily extrudable liquid ink into multi-centimeter scaled objects.
While the actual toxicity of Bisphenol A (BPA) is still debated, the direct measurement of BPA is difficult because of the weak response given by conventional electrochemical sensors, and current optical analysis methods are susceptible to the influence of interfering substances. A novel aptamer/graphene oxide FRET biosensor now provides a method for the rapid detection and risk assessment of BPA with high sensitivity and selectivity.
Molybdenum disulfide's (MoS2) semiconducting ability, strong light-matter interaction and similarity to the carbon-based graphene makes it of interest to scientists as a viable alternative to graphene in the manufacture of electronics, particularly photoelectronics. In particular, MoS2 has excellent optical properties when deposited as a single, atom-thick layer - unlike graphene, it emits light when excited; albeit relatively poorly. In order to realize the potential of atomically thin MoS2 as a nanoscale active material in a light source, a considerable enhancement of its emission efficiency is necessary.
Heat energy can be converted into electricity with very high efficiency through a temperature-induced electron flow process known as thermionic emission. Thermionic energy converters have been used with different heat sources, all of them requiring operation at high temperatures above 1500 K. A new study indicates that heat temperature can be lowered by an order of magnitude if using graphene as hot cathode. The findings indicate that a graphene-based cathode thermionic converter operating at 900 K could reach an efficiency of 45%.
In an effort to find a way to introduce folds or waves into graphene in a simple and large-scale way, researchers have invented a rubber-stamp printing method to introduce waves into the graphene. The ability to controllably form folds in graphene has significant research and technological applications. Induced folds have a sublithographic width and macroscopic length. They could be used as channel materials or interconnects in chips, and it has been shown that stable field emitters are formed by folded graphene.
The successful implementation of graphene-based devices invariably requires the precise patterning of graphene sheets at both the micrometer and nanometer scale. It appears that 3D-printing techniques are an attractive fabrication route towards three-dimensional graphene structures. Researchers have now used flakes of chemically modified graphene, namely graphene oxide GO and its reduced form rGO, together with very small amounts of a responsive polymer, to formulate water based ink or pastes to be used in 3D printers.
A comprehensive analysis of the fundamental properties, synthesis approaches and the future prospects of silicene, germanene, stanene, and phosphorene. It covers the literature on the fundamental properties of graphene analogous elemental sheets, inclusive of both theoretical and experimental knowledge. Various bottom-up synthesis techniques and top-down exfoliation approaches for the fabrication of two-dimensional elemental sheets are discussed.