One type of biomolecules, enzymes, regulate almost all chemical reactions involved in numerous biological processes in living organisms and are also widely used in research and industry. Regulation of enzyme activity and stability is very important and has always attracted great attention. Various enzyme regulators, ranging from proteins, peptides, and synthetic organic molecules, have been discovered. Recently, nanomaterials evolve as promising alternatives for enzyme modulation. Nanomaterials provide large surface areas for biomolecule adsorption and can be engineered to present multiple surface functional groups for interacting with biomolecules, such as enzymes and/or their substrates. In a recent study, scientists started to explore the interactions between functionalized graphene oxide and serine proteases, a large family of enzymes with important biomedical and industrial applications.
There is currently a very strong interest in using graphene for applications in optoelectronics. Graphene-based photodetectors have been realized before. By using graphene, researchers make use of the internal electric field that exists at the interface of graphene and metal. However, the low optical absorption of graphene - only 2.3 % due to its monoatomic thickness - leads to a low responsivity of these devices. Several groups worldwide are therefore currently pursuing different approaches to increase the interaction length of light with graphene and enhance the optical absorption. One novel approach is based on the integration of graphene into an optical microcavity. The increased electric field amplitude inside the cavity causes more energy to be absorbed, leading to a significant increase of the photoresponse.
Gallium Nitride (GaN) is a semiconductor material commonly used in bright light-emitting diodes since the 1990s, which are now found in traffic lights and solid-state lighting. Thanks to its wide band gap, this very hard semiconductor material also finds applications in optoelectronic, high-power and high-frequency devices. However, a severe problem that afflicts high-power GaN electronic and optoelectronic devices is self-heating and the difficulties of heat removal. Researchers have now found an unusual solution for the thermal management problem of gallium-nitride technology: They demonstrated that thermal management of GaN transistors can be substantially improved via introduction of alternative heat-escaping channels implemented with graphene multilayers.
It has been known for some time that graphene can be used for detection of individual gas molecules adsorbed on its surface - a graphene sensor can detect just a single molecule of a toxic gas. However, the extremely high sensitivity of graphene does not necessarily translate into its selectivity to various molecules. In other words, it can be detected that some molecules attached to the graphene surface change the resistivity of a graphene field-effect transistor but one cannot say what kind of a molecules have attached. Scientists have therefore thought that truly selective gas sensing with graphene devices requires the functionalization of graphene surface with some agents specific for different gas molecules. In new research, though, scientists have now found that chemical vapors change the noise spectra of graphene transistors. The noise signal for each gas is reproducible, opening the way for practical reliable and simple gas sensors made from graphene.
Graphene with its distinctive band structure and unique physiochemical properties - such as exceptionally low intrinsic electrical resistivity, high surface area, rapid electrode kinetics and good mechanical properties - is considered an attractive material for analytical electrochemistry. However, one of the key technical challenges for the use of graphene as functional material in device applications is the integration of nanoscale graphene onto micro- or millimeter sized sensing platforms. With a new methodology, a team from Florida International University was able to integrate graphene onto three-dimensional (3D) carbon microstructure arrays with good uniformity and controllable morphology.
Graphene-based materials are emerging as highly attractive materials for real applications, especially in the area of energy conversion and storage. There are four major energy-related areas where graphene will have an impact: solar cells, supercapacitors, lithium-ion batteries, and catalysis for fuel cells. A recent review gives a brief overview of the recent research concerning chemical and thermal approaches toward the production of well-defined graphene-based nanomaterials and their applications in energy-related areas. But before graphene-based nanomaterials and devices find widespread commercial use, two important problems have to be solved: one is the preparation of graphene-based nanomaterials with well-defined structures, and the other is the controllable fabrication of these materials into functional devices.
Early detection of pathogenic bacteria is critical to prevent disease outbreaks and preserve public health. This has led to urgent demands to develop highly efficient strategies for isolating and detecting this microorganism in connection to food safety, medical diagnostics, water quality, and counter-terrorism. A team of scientists has now developed a novel approach to interfacing passive, wireless graphene nanosensors onto biomaterials via silk bioresorption. The nanoscale nature of graphene allows for high adhesive conformality after biotransfer and highly sensitive detection. The team demonstrates their nanosensor by attaching it to a tooth for battery-free, remote monitoring of respiration and bacteria detection in saliva.
One of the greatest challenges in harnessing the power of nanotechnology is achieving dynamic control of mechanical, electronic, optical and chemical properties of nanoscale structures and devices. Dynamic control can be achieved through the use of piezoelectric materials. These are materials where applying a mechanical strain results in an electrical voltage or conversely, application of an electric field induces mechanical deformation. While piezoelectricity has mainly been shown for 3D bulk materials, the piezoelectric effect has also been demonstrated and exploited at the nanoscale. Researchers have now demonstrated through density functional theory calculations that piezoelectricity can be engineered into non-piezoelectric graphene by selective surface adsorption of atoms on only one side, which breaks inversion symmetry.