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Posted: Apr 29, 2014
Solving a mystery of thermoelectrics
(Nanowerk News) Materials that can be used for thermoelectric devices — those that turn a temperature difference into an electric voltage — have been known for decades. But until now there has been no good explanation for why just a few materials work well for these applications, while most others do not. Now researchers at MIT and elsewhere say they have finally found a theoretical explanation for the differences, which could lead to the discovery of new, improved thermoelectric materials.
This image shows the resonant bonding in lead telluride, one of the materials whose properties the team studied. It shows the calculated electron density distribution within the material. (Illustration courtesy of Sangyeop Lee)
For thermoelectric applications, Chen explains, “It is important to find a material with low thermal conductivity” — since thermoelectrics work by maintaining a temperature difference from one side of a device to the other. If a material conducts heat well, then heat leaks quickly from the hot side to the cold side, reducing its efficiency in converting heat to electricity. But predicting which materials have low conductivity — which is to say, those that are good thermal insulators — has proved elusive.
For example, some compounds that are good insulators are made up of elements similar to those found in other compounds that are not good insulators at all. “Why,” Chen wondered, “does one material have a low thermal conductivity, while another that is very similar does not?”
The solution to the puzzle turned out to come from work in other areas, including research to understand a different class called phase-change materials. These are being studied as a potential basis for computer memory devices that would retain information even when power is switched off. Phase-change materials change from an orderly, crystalline structure to a disordered structure in response to a change in temperature; they can then be switched back again with another temperature change.
Analysis of phase-change materials showed that they work because of a particular kind of chemical bonding, called resonant bonding — a type of bond in which electrons flip back and forth between several adjacent atoms. While resonant bonds’ effects on electrical and optical properties have been studied, nobody had previously examined their effect on thermal properties, Lee says.
“There is little communication between people doing phase-change research and those doing thermoelectric research,” Lee says. Interdisciplinary meetings at MIT helped lay the foundation for this research, he says: “This is an example where communication between people with different backgrounds can lead to new opportunities and boost understanding.”
It turns out that electrons’ “flipping” in resonant bonding leads to long-range interactions among their atoms, Chen says — producing the material’s low thermal conductivity.
Using first-principles calculations to account for such behavior with resonant bonding, Lee was able to demonstrate that this effect could explain known discrepancies between similar materials that of low and high thermal conductivity.
“We found some general rules which can be used to explain other materials,” Lee says.
This could lead to the discovery of new kinds of materials that also have very low thermal conductivity.
That, however, is just “one piece of the puzzle,” Chen says: In order to be useful for thermoelectric devices, a material must combine low thermal conductivity with high electrical conductivity. Figuring out which materials possess that combination of characteristics will require further research, he says.
David Broido, a professor of physics at Boston College who was not connected with this study, says that certain materials have long been known to have low thermal conductivity, “but the underlying reasons for this could not be explained by conventional theories of heat flow.” Now, this new research by Lee and Chen and their team “provides, for the first time, an explanation to this decades-old mystery.”
Broido says, “This paper thus gives new insight and fundamental understanding into the nature of heat flow in materials, and it also provides a new paradigm that opens the door” in the search for for new materials for both thermoelectric energy conversion and phase-change memory applications.