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Posted: Jan 20, 2016

Copper deposition to fabricate tiny 3D objects

(Nanowerk News) A new 3D microprinting process allows scientists to easily manufacture tiny, complex metal components. The used technology was designed by ETH researchers years ago for biological research and has now been further developed for a completely different application (Advanced Materials, "Template-Free 3D Microprinting of Metals Using a Force-Controlled Nanopipette for Layer-by-Layer Electrodeposition").
Scientists at ETH Zurich have developed a new method of 3D microprinting. This can be used to manufacture even tiny, partly overhanging structures easily and in a single step. One day, this could pave the way for the manufacture of complex watch components or microtools for keyhole surgery, for example.
movable micropipette (blue) to manufacture tiny copper objects
ETH researchers use a movable micropipette (blue) to manufacture tiny copper objects. (Visualisation: ETH Zurich / Alain Reiser)
In most existing 3D microprinting processes, overhanging structures can be achieved only through a workaround: during the printing process, a stencil manufactured beforehand is used as a placeholder under the overhang that is to be printed. The template must be removed once printing is complete. In the new technique developed by ETH doctoral student Luca Hirt of the Laboratory of Biosensors and Bioelectronics, the print head can also print sideways. This means that overhangs can be printed without templates.
Tiny pipette
The new technique is a refinement of the FluidFM system developed at ETH Zurich several years ago ("FluidFM: Combining Atomic Force Microscopy and Nanofluidics in a Universal Liquid Delivery System for Single Cell Applications and Beyond"). At the heart of this system is a moveable micropipette mounted on a leaf spring, which can be positioned extremely precisely. Nowadays, FluidFM is used primarily in biological research and medicine; for example, to sort and analyse cells and to inject substances into individual cells. For three years now, the system has been sold commercially by the ETH spin-off Cytosurge.
As part of his doctoral thesis at ETH Zurich, Luca Hirt has been investigating the possibility of using FluidFM for printing processes. In particular, he is interested in using this technique to electro-deposit dissolved metals and other substances on to a conductive substrate.
Tiny objects printed with FluidFM
Gallery: Tiny objects printed with FluidFM. The objects shown in these microscope images have a width of 15 to 35 micrometres. (All photos: ETH Zurich / Luca Hirt)
Electrochemical reactions at the tip
The system now developed works as follows: a droplet of liquid is placed on a base plate made of gold. The tip of the micropipette penetrates the droplet and acts as a print head. A copper sulphate solution flows slowly and steadily through the pipette. Using an electrode, the scientists apply a voltage between the droplet and the substrate, causing a chemical reaction under the pipette aperture. The copper sulphate emerging from the pipette reacts to form solid copper, which is deposited on the base plate as a tiny 3D pixel.
Using a computer to control the movement of the micropipette, the researchers can print three-dimensional objects pixel by pixel and layer by layer. The spatial resolution of this process depends on the size of the pipette’s aperture, which in turn determines the size of the copper deposits. At present, the scientists can produce individual 3D pixels with diameters ranging from 800 nanometres to more than five micrometres, and can combine these to form larger 3D objects. In an initial feasibility study, various spectacular microscopic objects were created. They consist of pure, non-porous copper and are mechanically stable, as studies by scientists from the group led by Ralph Spolenak, Professor of Nanometallurgy at ETH Zurich, showed. A particularly impressive object consists of three nested microspirals, which the ETH researchers manufactured in a single step and without using a template.
nested micro spirals
The 3D deposition process can even be used to manufacture nested spirals (microscope image; original width approx. 50 micrometres). (Photo: Hirt L et al., Advanced Materials 2016, reproduced with permission of Wiley-VCH)
“This method can be used to print not only copper but also other metals,” says Tomaso Zambelli, associate lecturer and group leader at the Laboratory of Biosensors and Bioelectronics at ETH Zurich. And FluidFM may even be suitable for 3D printing with polymers and composite materials, he says.
An advantage of the new method over other 3D microprinting processes is that the forces acting on the tip of the pipette can be measured via the deflection of the leaf spring on which the micropipette is mounted. “We can use this signal as feedback. Unlike other 3D printing systems, ours can detect which areas of the object have already been printed,” says Hirt. This will make it easier to automate the printing process.
Successful collaboration with a spin-off
The scientists have submitted a patent application for the method. The ETH spin-off Cytosurge has now licensed the method from ETH Zurich. Pascal Behr played a key role in developing FluidFM at ETH several years ago. Today, he is CEO of Cytosurge. “We see big market potential in the printing process and an opportunity to further diversify our company,” he says. “We are convinced of the idea of using FluidFM in 3D microprinting. Now, the task is to optimise this application in collaboration with interested researchers at universities and in industry – for example, in the watchmaking, medical technology and automotive sectors.” Behr sees an initial application in the field of rapid prototyping, where microscopic components can be manufactured quickly and easily using 3D printing.
The long-established collaboration between ETH Zurich and Cytosurge will also continue. “It is a case of mutual give and take, from which both sides profit,” says Zambelli. Cytosurge provides ETH with its latest equipment, which the ETH scientists are able to use for their research. They in turn help to test the devices and offer suggestions for improvements and further development.
Source: ETH Zurich
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