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Posted: Mar 28, 2016

Engineering ultralight, high-dense nanoporous gold

(Nanowerk News) A team of Korean research team, led by Professor Ju-Young Kim (School of Materials Science and Engineering) of Ulsan National Institute of Science and Technology (UNIST), South Korea has recently announced that they have successfully developed a way to fabricate an ultralight, high-dense nanoporous gold (np-Au).
In a new paper, published in Nano Letters ("Weakened Flexural Strength of Nanocrystalline Nanoporous Gold by Grain Refinement") on March 22, the team reported that this newly developed material, which they have dubbed "Black Gold" is twice more solid and 30% lighter than standard gold.
formation of nanoporosity in free corrosion dealloying for gold samples
These are SME images that show the formation of nanoporosity in free corrosion dealloying for gold samples. (Image: UNIST)
According to Prof. Kim, "This particular nanoporous gold has a 100,000 times wider surface when compared to standard gold. Moreover, due to its chemically stablity, it is also harmless to humans."
The surfaces of np-Au are rough and the metal loses its shine and eventually turns black when they are at sizes less than 100 nanometres. This is the reason that they are called "Black Gold".
In their study, the team investigated grain boundaries in nanocrystalline np-Au and found a way to overcome the weakening mechanisms of this material, thereby suggesting its usefulness.
The team used a ball milling technique to increase the flexural strength of the three gold-silver precursor alloys. Then, using free corrosion dealloying of silver from gold-silver alloys, they were able to achieve the nanoporous surface. According to the team, "The size of the pores can be controlled by the temperature and concentration of nitrate." Moreover, they also note that this crack-free nanoporous gold samples are reported to exhibit excellent durability in three-point bending tests.
Prof. Kim's team notes, "Ball-milled np-Au has a much greater density of two-dimensional defects than annealed and prestrained np-Au, where intergranular fracture is preferred." They continue, "Therefore, the probable existence of grain boundary opening in the highest tensile region is attributed to the flexural strength of np-Au."
They suggest that this newly developed technique can be also applied to many other metal, as the np-Au produced by this technique have shown increased strength and durability while still maintaining the good qualities of standard gold.
This means that this technique can be also used in other technologies, like catalytic-converting as observed by platinum, the automobile catalyst and palladium, the hydrogen sensor catalyst.
Source: Ulsan National Institute of Science and Technology (UNIST)
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