The latest news from academia, regulators
research labs and other things of interest
Posted: Jun 23, 2017
New form of carbon discovered that is harder than diamond but flexible as rubber
(Nanowerk News) Scientists have found a way to make carbon both very hard and very stretchy by heating it under high pressure. This “compressed glassy carbon”, developed by researchers in China and the US, is also lightweight and could potentially be made in very large quantities (Science Advances, "Compressed glassy carbon: An ultrastrong and elastic interpenetrating graphene network"). This means it might be a good fit for several sorts of applications, from bulletproof vests to new kinds of electronic devices.
Carbon is a special element because of the way its atoms can form different types of bonds with each other and so form different structures. For example, carbon atoms joined entirely by sp3 bonds produce diamond, and those joined entirely by sp2 bonds produce graphite, which can also be separated into single layers of atoms known as graphene. Another form of carbon, known as glassy carbon, is also made from sp˛ and has properties of both graphite and ceramics.
But the new compressed glassy carbon has a mix of spł and sp˛ bonds, which is what gives it its unusual properties. To make atomic bonds you need some additional energy. When the researchers squeezed several sheets of graphene together at high temperatures, they found certain carbon atoms were exactly in the right position to form sp3 bonds between the layers.
Bond, sp3 bond. Timothy Strobel
By studying the new material in detail, they found that just over one in five of all its bonds were sp3. This means that most of the atoms are still arranged in a graphene-like structure, but the new bonds make it look more like a large, interconnected network and give it greater strength. Over the small scale of individual graphene sheets, the atoms are arranged in an orderly, hexagonal pattern. But on a larger scale, the sheets are arranged in a disorderly fashion. This is probably what gives it the combined properties of hardness and flexibility.
The researchers made the compressed glassy carbon using a relatively simple method that could be reproduced on a large scale easily and cheaply. In simple terms, they used a sort of machine press that applies high-pressure loads to the carbon. But this must have involved several tricks to control the pressure and temperature in exactly the right way. This would have been a time-consuming process but should still be achievable for other people replicate the results.
Carbon materials are continually surprising us – and the emphasis of research has been to find or cook things in between its natural forms of diamond and graphite. This new form is the latest of what seem like limitless ways you can bond carbon atoms, following on from the discovery of graphene, cylindrical carbon nanotubes and spherical buckminsterfullerene molecules.
A material like this – that is strong, hard, lightweight and flexible – will be in high demand and could be used for all sorts of applications. For example, military uses could involve shields for jets and helicopters. In electronics, lightweight, cheaply manufactured materials with similar properties to silicon that could also have new abilities could provide a way to overcome the limitations of existing microchips.
The dream is to find a carbon material that could replace silicon altogether. What is needed is something that allows electrons to move through it quickly and whose electrons can easily be placed into an excited state to represent the on and off functions of a transistor. The researchers behind glassy carbon haven’t studied these properties in the new material so we don’t yet know how suitable it might be. But it might not be that long until another of carbon is found. So far, decades of hunting hasn’t turned up what we need, but maybe we just have to look deep down to find it.
Source: By Elton Santos, Research Fellow, School of Mathematics and Physics, Queen's University Belfast