Graphene aerogel holds record as world's least dense 3-D printed structure

(Nanowerk News) The world's lightest 3-D printed structure is so lightweight that it can be placed on top of a cotton ball or the petals of a flower.
The record-breaking material is 3-D printed graphene aerogel and it was developed by Dong Lin, Kansas State University assistant professor of industrial and manufacturing systems engineering; Chi Zhou, assistant professor of industrial and systems engineering at University at Buffalo; and Qiangqiang Zhang, an associate professor at Lanzhou University in China.
GUINNESS WORLD RECORDS has named the graphene aerogel as "the least dense 3-D printed structure." The 3-D printed graphene aerogel weighs 0.5 milligrams per cubic centimeter. The researchers developed the material in February 2016 and have received the official recognition from GUINNESS WORLD RECORDS. Their achievement will be featured in the GUINNESS WORLD RECORDS 2018 Edition.
Dong Lin, Kansas State University assistant professor of industrial and manufacturing systems engineering, describes the 3-D printed graphene aerogel that he co-developed with researchers at the University at Buffalo and Lanzhou University in China. GUINNESS WORLD RECORDS has named the graphene aerogel as the world's least dense 3-D printed structure.
"Graphene is a revolutionary material and it makes sense that its aerogel form would be just as important," Lin said. "Our 3-D printed graphene aerogel has important properties that give the material many applications for better electronics, batteries or semiconductors."
Not only is the 3-D printed material groundbreaking, but the way the researchers print the three-dimensional graphene is just as revolutionary.
Graphene is a single atom-thick sheet of hexagonally coordinated carbon atoms, which makes it the world's thinnest material and gives it valuable physical and electronic properties.
To 3-D print graphene aerogel, the researchers use a modified inkjet printer that uses two nozzles. They 3-D print droplets of a graphene oxide and water mixture in a freezer on a cold plate that is minus 20 degrees Celsius. This method creates a 3-D ice structure of graphene and frozen water, which helps the graphene to maintain its shape, Lin said.
When printing is complete, the researchers place the 3-D material in a freeze dryer, which removes the ice by providing high vacuum and low temperature. What's left is a three-dimensional graphene aerogel that maintains its shape at room temperature.
3-D printed graphene aerogel
A square sample of 3-D printed graphene aerogel is so lightweight that a wheat plant's individual awn can hold it without bending. (click on image to enlarge)
"We didn't plan on setting a record, but it's certainly a nice recognition of our work," Zhou said. "I think this helps show the enormous potential that graphene aerogel has in our daily lives."
It has been notoriously difficult to create three-dimensional graphene shapes, Lin said, and his collaborative team is the third group in the world to 3-D print graphene. Their new printing method is an improvement because it uses fewer ingredients and only requires graphene oxide and frozen water. Additionally, the two nozzles on the modified printer enable the researchers to create complex shapes with less material, which makes it the lightest material in the world.
"With this 3-D printing method, we can control the shape of the graphene aerogel and ideally, we can control the electric and mechanical properties for the aerogels, too," Lin said.
The graphene aerogel has numerous possibilities, from flexible batteries to better semiconductors, and it could even be used to make better insulation in the construction of buildings.
"Aerogel is a special material with a lot of applications and that's why it is one of the hottest materials throughout the world," Lin said.
Source: Kansas State University