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Posted: Aug 31, 2011
Sticky nanomaterials - copying geckos' toes
(Nanowerk News) Geckos are famous for their ability to walk up walls and scamper across ceilings. The dry-adhesive surface of geckos' toes has inspired many attempts to copy this ability in an artificial material. Isabel Rodríguez at the A*STAR Institute of Materials Research and Engineering and co-workers at Nanyang Technological University in Singapore have now made one of the closest mimics to gecko toes yet, and shown that it has the properties to match ("Fabrication and Analysis of Gecko-Inspired Hierarchical Polymer Nanosetae").
Artificial hairs just a few hundred nanometers in diameter mimic the adhesive surface of a gecko's toe-pads.
The geckos' ability to cling to surfaces is not due to glue but to the millions of microscopic hairs that coat the surface of their toes. Each hair has a branched, hierarchical structure—toward its tip, each fiber breaks into multiple sub-fibers, which in turn break into hundreds of fibrils 100–200 nanometers in diameter. This structure ensures a high surface area, which helps the gecko to cling to the wall. In addition, the hairs become more flexible as they become thinner, which helps to maximize the number of fibrils in contact with the wall.
Rodríguez and her co-workers have successfully mimicked this hierarchical structure through the use of an anodization technique that allows branched nanopores to be etched controllably into sheets of aluminum foil—a process they used to form templates with which to create the dry adhesive surface. These templates were stamped into sheets of polycarbonate plastic using a process known as capillary force-assisted nanoimprinting, forming a hairy polycarbonate surface.
To evaluate the qualities of the hierarchical hair structure, the researchers created two separate surfaces: one with simple, unbranched hairs; and one in which the hairs branched at their tips to form nanoscopic fibrils (pictured) closely resembling those found on gecko toe-pads. They found that the sheer adhesion force of the branched material was 150% greater than that of the linear material.
"One of the most important findings from the study is the insight of how the fibrils can be made using a simple process," says Rodríguez. "There have been reports of other hierarchical structures fabricated in polymers, but the fabrication methods they use are rather costly and complicated and not suitable for large scale." The relatively high cost of previous attempts is due to the way the template is made—a problem that the team have now overcome using their porous alumina template technology. "Our branched, porous template fabrication is straightforward and allows large areas of gecko-like structures to be fabricated at low cost," she adds.