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Posted: Jul 29, 2016
Boron boosts graphene's sensitivity to noxious gases
(Nanowerk News) Detecting noxious gases, such as those released from power plants and other sources that can harm the environment, is something graphene does well, but it could be even better.
Researchers discovered a way to significantly improve its performance by peppering high-quality graphene sheets with boron impurities. Compared to pristine graphene, these modified sheets, a.k.a. boron-doped graphene, were 27 times more sensitive at detecting nitrogen dioxide and 105 times more sensitive at detecting ammonia ("Ultrasensitive gas detection of large-area boron-doped graphene").
Experimental observations (left) confirm theory-based simulations (right) of boron-doped graphene. Boomerang-shaped atomic features revealed in a centimeter-wide sheet of boron-doped graphene are associated with enhanced sensitivities for nitrogen dioxide and ammonia detection.
Ultrasensitive gas detectors based on this proof-of-principle experiment could monitor environmental health and safety. Sheets of doped graphene with useful electronic and magnetic properties could also find application in field-effect transistors, hydrogen storage, and lithium-ion batteries.
Theory predicts that graphene could be much better at detecting noxious gases if impurities, or dopants, were incorporated into its rigid framework of one-atom-thick carbon. Experimental progress, however, has been limited by a lack of high-quality boron-doped graphene.
Here, scientists grew highly ordered, centimeter-wide sheets of boron-doped graphene and observed, for the first time, boomerang-shaped features corresponding to dopant atoms embedded within graphene’s hexagonal matrix. They characterized the material’s electronic properties, which depend on how impurity atoms incorporate into graphene’s honeycomb lattice and create defects that change the way gases chemically interact with graphene, which in turn alters current flow.
To discover the atomic-level details of how boron doping changes graphene’s properties, the researchers went to the Center for Nanophase Materials Sciences, a DOE Office of Science User Facility at Oak Ridge National Laboratory, for advanced instrumentation and expertise in low-voltage electron microscopy and scanning tunneling microscopy.
Results showed that, compared with pristine graphene, boron doping increases the gas sensing capability of graphene to parts per billion for nitrogen dioxide and parts per million for ammonia.