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Posted: Jul 31, 2017
Extracting hydrogen from water cheaply and efficiently
(Nanowerk News) Lawrence Livermore scientists have developed a technique that helps extract hydrogen from water efficiently and cheaply.
Hydrogen can be used as a clean fuel in fuel cells, which produce power with water and heat as the only byproducts. As a zero-emission fuel, the hydrogen can be recombined with oxygen to produce electric power on demand, such as onboard a fuel-cell vehicle.
Hydrogen gas bubbles evolve from water at tantalum disulfide electrocatalyst surfaces. Catalytic activity in layered metal dichalcogenides like these is usually limited to edges, but this work reports new materials that also can generate hydrogen at the surfaces. (Image: Ryan Chen/LLNL)
"Hydrogen gas has immense potential as a source of sustainable fuel, because it generates no carbon emissions," said Lawrence Livermore lead author Brandon Wood. "It can be produced from multiple sources, but the holy grail is to make it from water." Wood also is a principal investigator in the Department of Energy Office of Energy Efficiency and Renewable Energy's (EERE) HydroGEN Advanced Water Splitting Materials Consortium, an Energy Materials Network node focused on hydrogen production from water.
Extracting hydrogen from water using electricity is a fairly straightforward process, but it is inefficient and usually takes a lot of energy. The efficiency can be improved using catalysts, which are often made of expensive precious metals, such as platinum.
The Lawrence Livermore team sought to come up with a cheaper way to efficiently split the water molecules.
To solve the problem, Wood and lead author Yuanyue Liu -- a Livermore summer intern with Wood -- turned to a class of catalysts based on transition-metal dichalcogenides (MX2), which have generated a great deal of interest for water splitting. The issue with the MX2 materials that currently are used (based on molybdenum and tungsten) is that only the exposed edges of the catalysts are active. Instead, Wood, Liu and colleagues used quantum-mechanical calculations to reveal underlying electronic factors that would make the entire surfaces of the MX2 materials active for catalysis. These "descriptors" were then used to computationally screen MX2 candidates that could make better water-splitting catalysts.
Researchers from Rice University experimentally validated the calculations by synthesizing and testing two of the proposed materials, tantalum disulfide and niobium disulfide. Beyond confirming that the materials' surfaces were active towards water splitting, they discovered that the materials had an unusual ability to optimize their shape as they evolved hydrogen gas. This allowed the materials to achieve even better performance.
"The self-optimizing behavior and surface activity mean high performance can be achieved with only minimal catalyst loading," Wood said. "It's a huge advantage for scalable processing, since there's no need to turn to expensive techniques like nanostructuring. Our work opens the door to using this type of catalyst, and our theoretical descriptor should make it easy to assess water-splitting activity in similar classes of layered materials."