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Creating surfaces that repel water and control its flow

(Nanowerk News) To prevent water and ice from making our shoes soggy, frosting our car windows and weighing down power lines with icicles, scientists have been exploring new coatings that can repel water. Now one team has developed a way to direct where the water goes when it's pushed away.
Their report appears in the journal ACS Applied Materials & Interfaces ("Superhydrophobic, Low-Hysteresis Patterning Chemistry for Water-Drop Manipulation").
Repelling water droplets and controlling their flow depends on water maintaining its spherical shape.
Water-repelling, or superhyrdophobic, materials are already commercially available. But when blown by wind or subjected to a slight tilt, the water droplets on these surfaces will glide away in a direction determined by the initial nudge. To gain better control over the flow of water on superhydrophobic materials, scientists have been etching paths into coatings for the liquid to follow. And although water will take the designated path, it can leave behind a wet trail.
Previous studies suggest that on these paths, rolling droplets have a different contact angle at the front and back-- they're rounded in front but flatter in the back -- and this causes the wet residue. Thomas McCarthy and colleagues wanted to address this shortcoming by aiming for more rounded droplets.
The researchers started with superhydrophobic silicon wafers, in which they cut straight, circular and wavy tracks using photolithography. Then they exposed the material to an oxygen plasma cleaner and treated it with a vapor of silicone nanofilaments to make the tracks hydrophobic. This novel step was critical for keeping water droplets' spherical shape and minimizing the difference in the front and back contact angles.
Testing showed that water flowed along the designated paths without leaving a trace. Watch this Headline Science video to see how the material works.
Source: American Chemical Society
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