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Posted: Feb 23, 2018
Luminescent nano-architectures of gallium arsenide
(Nanowerk News) A team at the Helmholtz Zentrum Berlin (HZB) has succeeded in growing nanocrystals of gallium arsenide on tiny columns of silicon and germanium. This enables extremely efficient optoelectronic components for important frequency ranges to be realised on silicon chips.
The GaAs nanocrystal has been deposited on top of a silicon germanium needle, as shown by this SEM-image. The rhombic facets have been colored artificially. (Image: S. Schmitt/HZB)
Gallium arsenide semiconductors have better optoelectronic properties compared to silicon. Those properties can be controlled and altered by specific nanostructures.
Dr. Sebastian Schmitt, Prof. Silke Christiansen and their collaborators have succeeded to obtain such a nanostructure on a silicon wafer covered with a thin, surprisingly crystalline layer of germanium. Colleagues from Australia had produced the high-quality wafer and sent it to HZB. The thin film of germanium facilitates the growth of gallium arsenide crystals because the lattice constants of germanium and gallium arsenide are almost identical.
The nano-architecture looks spectacular under the electron microscope. At first glance, it seems as if you can see a cube on the tip of each silicon needle. At second glance, it becomes apparent that it is actually a rhombic dodecahedron – with each of the twelve surfaces an identical rhombus.
Intensity distribution of the six optical modes in the rhombic-dodecahedron is shown along two rectangular cross sectional planes. (Image: HZB) (click on image to enlarge)
This nano-structure exhibits unusually high optical emission after excitation with a laser, especially in the near-infrared region. “As the GaAs crystals grow, germanium atoms also become incorporated into the crystal lattice”, explains Schmitt. This incorporation of germanium leads to additional discrete energy levels for charge carriers that emit light when falling back to their original levels. The light is then amplified by means of optical resonances in the highly symmetrical nanocrystal, and the frequency of these resonances can be controlled by size and geometry of the crystals. A large number of these so-called photonic resonances could be detected in the experiment that also agree well with numerical calculations.
“Because the optical and electronic properties of semiconductors can be strongly modified by nanostructuring, such nano-architectures are well suited for developing novel sensors, light-emitting diodes, and solar cells”, says Schmitt.