New glass-like polymer could conduct electricity for transparent electronics

(Nanowerk News) Purdue researchers have created a transparent polymer film that also conducts electricity, introducing an inexpensive organic material for applications such as the screens of electronic devices.
While some polymers can already conduct electricity with the help of a process called chemical doping, none have yet been made that conduct just as well in a transparent form. This combination could find use in TV, phone and computer screens that currently use a relatively expensive inorganic material, indium tin oxide, to serve as a transparent conductor. The researchers detail their discovery in a paper published in Science ("A nonconjugated radical polymer glass with high electrical conductivity").
“The precursors of this new polymer are made on the ton scale,” said Bryan Boudouris, the Robert and Sally Weist Associate Professor of Chemical Engineering. “Having a conducting transparent material from carbon-based materials would be significant.”
The polymer film, which has the look and feel of glass, can be more cheaply produced on a large scale than indium tin oxide because it originates from earth-abundant materials. Its cost effectiveness also has advantages over polymers already used for electronics that rely on expensive chemistry and chemical doping to achieve high conductivity. Existing conducting polymers also typically absorb light due to their conjugated, or delocalized, electron network structure.
“It’s tough to engineer something that is conjugated to be transparent,” said Brett Savoie, an assistant professor of Chemical Engineering. “So, we started with a completely new non-conjugated polymer and modified it to conduct.”
Modifications involved adding radical groups that are already transparent but typically wouldn’t conduct electricity within a polymer. “Our idea was, could we use polymers easier to make on a large scale but also get them to be electronically active?” Boudouris said.
Savoie simulated how the radical groups electronically communicate with each other across the polymeric material, a property known as electrical percolation, to figure out how to make the polymer a good conductor. The simulations showed that it was critical to incorporate more radicals than previous studies had been able to achieve, and also make the polymer soft enough that the radical groups could associate within the material. Boudouris accomplished this by synthesizing a material that had both a high density of radical sites and could flow at low temperatures, resulting in a transparent film processed near room temperature.
high density of transparent radical groups (light regions) enable a polymer to conduct electricity despite non-conducting areas (dark regions)
An artistic rendering shows how a high density of transparent radical groups (light regions) enable a polymer to conduct electricity despite non-conducting areas (dark regions). (Image: Brett Savoie, Purdue University)
This polymer is not only transparent, but could conduct electricity competitively with commercially available conjugated polymers. “The simulations gave us the design principles that will allow us to make even better conductors in the future,” Boudouris said.
The new polymer also provides insights for future research to be conducted by Boudouris, Savoie and other faculty at the Purdue-based Materials Innovation for Bioelectronics from Intrinsically-stretchable Organics (Mi-Bio) center, which aims to produce tailor-made polymers for biomedical applications.
“Conducting polymers are different from other conductors in that they can reversibly exchange ions and analytes with liquid media—kind of like a sponge—and this creates all kinds of interesting sensing and device applications.” Savoie said.
Source: Purdue University
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