| Aug 18, 2022 |
Considering how friction is maximised when liquids flow on nanoscales(Nanowerk News) The dynamics of how liquids behave when confined in a nanoscale-sized space such as nanochannels, nanotubes or nanopores, is key to understanding a wealth of processes including lubrication, filtration and even energy storage. |
| The dynamics of liquids at nanoscales are different to behaviour in confinement at macroscales, however. One of the key differences that a reduction in scale creates is friction and shear between the liquid and its solid container. And further complications arise in systems with solid-to-solid contact with features like wear, micro-pitting and scuffing created. |
| A new paper published in EPJ E ("Maximizing Friction by Liquid Flow Clogging in Confinement") and authored by Shan Chen, from the State Key Laboratory of Organic-Inorganic Composites at Beijing University of Chemical Technology, China, uses simulations of molecular dynamics to look at the friction-induced nano-confined liquids. |
 |
| A cross-section of simulations of several different flow types with pistons placed at different positions. (Image: S. Chen et al, 2022) |
| The simulation was created using the Molecular Massively Parallel Simulator (LAMMPS) which facilitated the investigation of how the properties of a confined liquid cooperatively affect the friction force between a liquid column and confining solid substrates. The authors considered three different flow types and assessed how these changed with fluid velocity. |
| The team simulated flows of Lennard-Jones (LJ) chain-like liquid encaged in a solid cylindrical nanopore with atomically smooth surfaces. To replicate the effect of solid/solid contact on liquid/solid friction, the authors introduce model geometries through pistons. |
| One of these pistons was placed on the left side of the confined liquid, and provided a driving force pushing the fluid column, while the piston on the right side was freely movable. |
| The resultant simulation reveals the existence of a variable previously not considered — molecular clogging — on liquid/solid friction. This arises in the strongly confined liquid, the researchers say, from the aforementioned solid to solid contact. |
| This results in a modified flow sharing features of plug and Poiseuille flow — the flow of liquid between two infinitely long parallel plates — that is different at the nanoscale than the standard Poiseuille flow observed at the macroscale. |
| Source: By Robert Lea, SciencePOD |
