High-resolution measurement of photocurrents in single-nanotube devices

(Nanowerk News) The continuing trend toward miniaturization in electronics demands the use of new materials. Components made of carbon nanotubes may meet this need – and the properties of single nanotube devices can now be characterized with the required resolution.
Given the demand for further miniaturization of electronic components, current silicon-based technology will soon reach its limits, set by fundamental physical and technical parameters. Minute hollow cylinders made from sheets of carbon, so-called carbon nanotubes, have the potential to exceed these limits. Not only can single carbon nanotubes be utilized as transistors, they can also absorb and emit light.
The walls of these tubes are around 1 nanometer (nm) thick. Ideally, their optical and electrical properties should be characterized at a comparable scale. LMU professor Achim Hartschuh and his team have used an optical antenna – a tiny gold pin with a sharp tip that is irradiated with a laser – to simultaneously measure electrical and optical signals from nanotubes with nanoscale precision (see paper in ACS Nano: "Antenna-Enhanced Photocurrent Microscopy on Single-Walled Carbon Nanotubes at 30 nm Resolution"). Conventional methods based on confocal microscopy do not attain this level of spatial resolution.
Characterizing devices made of nanotubes
Using an optical antenna allows one to amplify the signals emitted by single nanotubes and map these with very high resolution. "In our study, we have measured photocurrents along single carbon nanotubes with a resolution of less than 30 nm," says Hartschuh. He and his colleagues have already used this method, called tip-amplified optical near-field microscopy, in many other settings, and have now developed it still further.
The spatial resolution of the photocurrent measurements corresponds closely to the theoretically expected level. And Hartschuh, who is a member of LMU's Center for NanoScience (CeNS) and is involved in the Nanosystems Initiative Munich (NIM) points to further possible applications of the technique: "In addition to the carbon nanotubes employed here, our method could be applied to inorganic semiconducting nanowires, and perhaps to solar cells and the materials used to fabricate them," he says.
Source: Ludwig-Maximilians-Universität München (LMU)
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