Researchers turn potato chip bags into energy-saving cooling films

(Nanowerk News) Aluminium-plastic composite (APL) films are very often used for food packaging, but they pose a challenge when it comes to plastic recycling. Researchers led by Bayreuth-based physical chemist Prof. Dr. Markus Retsch have now developed an upcycling process that gives such films an innovative second use. An easy-to-apply coating transforms used APL packaging into high-performance, versatile cooling films that counteract another global problem: the high energy demand for cooling systems.
The research results are presented in the journals ACS Sustainable Chemistry & Engineering ("Passive Daytime Cooling Foils for Everyone: A Scalable Lamination Process Based on Upcycling Aluminum-Coated Chips Bags") and Advanced Materials Technologies ("Upcycling Chips-Bags for Passive Daytime Cooling").
Passive day cooling does not absorb solar radiation and emits thermal energy into space
Passive day cooling does not absorb solar radiation and emits thermal energy into space. Materials with passive cooling properties can be used on awnings, blinds or roofs. (Image: Daniela Leitner)
Films made of aluminium-plastic laminates (APL) have long been used extensively to extend the shelf life of chips, roasted and powdered coffee, milk, fruit juices and other foods. During the Covid 19 pandemic, they were used to package FFP2 masks and rapid tests. The films consist of several polymer layers and an aluminium layer, which protects the products from damaging factors – especially from sunlight and heat, but also from moisture and oxygen. However, recycling such composite films is difficult as a result of this combination of different materials.
The upcycling process of chips bags now developed in Bayreuth shows a way to improve the recycling of APL waste and, at the same time, reduce global energy consumption. Cooling systems already account for around 15 % of global energy consumption, and in view of climate change and the occurrence of heat waves, this share threatens to continue to rise.
The aluminium layer of APL packaging provides a mirror-like reflective surface, such as that found on emergency blankets. If a clear polymer layer is now applied that increases the radiation of thermal energy, a powerful cooling system is complete. A simple laminating film, such as is commonly found in office supply stores, is already sufficient as a material for the coating.
The coating creates cooling foils that can be applied to any surface in the open air – such as umbrellas, blinds and awnings – and thus prevent heating from glaring sunlight. At the same time, the ambient heat is diverted to the cool space without the need for an external energy supply. These effects are referred to as "passive daytime cooling". Ideally, they can lead to temperatures below the ambient temperature, even in the case of intense sunlight.
Passive daytime cooling is made possible by the fact that the materials used meet special optical requirements. They must scatter or reflect as much of the sunlight as possible, which has a wavelength between 0.3 and 2.5 micrometres. On the other hand, in the wavelength range between 8 and 13 micrometres, the so-called sky window, they must emit as much thermal energy as possible into space in the form of infrared radiation. Aluminium-plastic composite foils fulfil these requirements very well.
Using the example of coated commercial potato chips bags, the Bayreuth researchers have demonstrated: Around 87 % of the sunlight is reflected by the aluminium layer. The additional polymer coating of the new sustainable cooling foils improves the radiation in the wavelength range of the sky window and thus emits heat directly into space.
Prof. Dr. Markus Retsch and his colleague Dr. Qimeng Song have tested different ways of turning potato chip bags and other APL packaging into efficient cooling materials. Industrial processes that use polydimethylsiloxane (PDMS) as a coating material are possible. But as the recent study published in "ACS Sustainable Chemistry & Engineering" shows, it is also conceivable that the coating process could be undertaken by anybody in the future. Simple commercial laminating equipment is all that is needed to turn old APL packaging into cooling materials that can be used as heat shields on patios, balconies, exterior walls or roofs.
Source: University of Bayreuth (Note: Content may be edited for style and length)
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