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Posted: Jan 14, 2014
Stain-free, self-cleaning clothing on the horizon
(Nanowerk News) The researchers behind SLIPS (Slippery Liquid-Infused Porous Surfaces) have demonstrated a spate of sleek applications of the super-slick coating since unveiling it in a 2011 issue of Nature – and they just expanded its repertoire even more.
The team from Harvard's Wyss Institute and the School of Engineering and Applied Sciences (SEAS) has demonstrated the uncanny ability of SLIPS – inspired by the pitcher plant – to repel nearly any material it contacts: water, ice, oil, saltwater, wax, blood, and more. They have demonstrated its versatility under extreme conditions of pH and temperature, and have successfully used SLIPS to coat everything from refrigeration coils to lenses, windows, and ceramics. What's more, in 2012 they won an R&D 100 Award for the technology from R&D Magazine. This annual award honors the year's 100 most significant products, the so-called game-changers of the technology scene.
And now, as reported January 10 in a special issue celebrating the 25th year of the journal Nanotechnology ("Fabrics coated with lubricated nanostructures display robust omniphobicity"), the team has modified everyday cotton and polyester fabrics to exhibit traditional antifouling SLIPS behavior. The advance could meet the need for a robust, stain-resistant textile for a host of consumer and industrial applications.
Using SLIPS to create omnirepellent fabrics involves treating the material with a liquid-infused coating that changes the fabric's chemical properties. Oil, water, and other substances then bead up and roll right off the fabric. (Image courtesy of Joanna Aizenberg and James C. Weaver.)
"We took one page out of Nature's book, and are finding that it has the potential to help us develop solutions to a variety of age-old challenges: ice we don't want on refrigeration coils, bacteria that we don't want on medical devices, and now stains we don't want on clothes," said Joanna Aizenberg, Ph.D., who leads the development of the technology. Aizenberg is a Core Faculty member of the Wyss Institute and the Amy Smith Berylson Professor of Materials Science at SEAS
Most currently available state-of-the-art, stain-resistant fabrics draw their inspiration and design from the lotus leaf. Tiny nanotextures on the surface of lotus leaves resist water, causing droplets of water to bead up on a cushion of air at the edge of the surface. Lotus-inspired textiles therefore use air-filled nanostructures to repel water. These are capable of repelling most aqueous liquids and dirt particles, but they suffer from a series of shortcomings, explained Cicely Shillingford, a Wyss Research Assistant and lead author of the Nanotechnology publication. They require a stable solid-air layer for the beading process to occur and thus fail easily under pressure – as in a heavy rainstorm – and do not withstand physical damage, such as twisting and abrasion, very well. They also stain more easily from organic or complex liquids, such as oil.
On the other hand, SLIPS is inspired by the carnivorous pitcher plant, which locks in a water layer to create a slick coating that causes insects that land on it to literally hydroplane and fall into the plant. The SLIPS coating anchors a slippery lubricated film infused to a nanoporous solid surface, creating a material that performs exceedingly well under pressure or physical damage, and can resist all kinds of liquids, including oil.
To create a fabric with SLIPS-type functionality, the team bought off-the-shelf cotton and polyester fabrics from stores near their lab in Cambridge, Massachusetts, and developed two ways to chemically treat them. One involved coating them with tiny particles of silica (SiM), and the other required a treatment with sol-gel based alumina (SgB).
What happened after the team put the SLIPS-fabrics through a ringer of tests performed according to industrial standards – from twisting to rubbing and staining attempts?
"The SLIPS-fabric showed an unprecedented ability to repel a wide range of fluids and resist staining, and it handles physical stresses and strains just fine," said Aizenberg.
While not every SLIPS-fabric was as breathable (yet) as the researchers hoped, it outperformed currently available stain-resistant fabrics on just about every other measure. As such, the most likely immediate applications could be fabrics needed in potentially extreme environments where breathability is not paramount but exposure to challenging contaminating liquids and biological hazards is involved, such as tactical suits for the military, lab coats, medical clothing, specialty garments for construction and manufacturing, and perhaps even tents and sports stadiums.
"We're very excited about the robustness of the SLIPS technology platform," Aizenberg said.
The latest work was supported by the Advanced Research Projects Agency-Energy (ARPA-E), US Department of Energy, and the Wyss Institute for Biologically Inspired Engineering at Harvard University.