Open menu

Nanotechnology General News

The latest news from academia, regulators
research labs and other things of interest

Posted: Oct 19, 2015

'Molecular accordion' drives thermoelectric behavior in promising material

(Nanowerk News) Engines, laptops and power plants generate waste heat. Thermoelectric materials, which convert temperature gradients to electricity and vice versa, can recover some of that heat and improve energy efficiency. A team of scientists at the Department of Energy's Oak Ridge National Laboratory explored the fundamental physics of the world's best thermoelectric material--tin selenide--using neutron scattering and computer simulations. Their new understanding of the origin of atomic dynamics in this material, published in Nature Physics ("Orbitally driven giant phonon anharmonicity in SnSe"), may aid research in energy sustainability and enable the design of materials that efficiently convert heat into electricity.
Redistribution of electronic clouds causes a lattice instability and freezes the flow of heat in highly efficient tin selenide
Redistribution of electronic clouds causes a lattice instability and freezes the flow of heat in highly efficient tin selenide. The crystal lattice adopts a distorted state in which the chemical bonds are stretched into an accordion-like configuration, and makes an excellent thermoelectric because heat propagation is thwarted. (Image: Oak Ridge National Laboratory, U.S. Dept. of Energy) (click on image to enlarge)
"We performed the first comprehensive measurements of atomic vibrations in this important new thermoelectric material," said senior author Olivier Delaire in ORNL's Materials Science and Technology Division. "We discovered the origin of its very low thermal conductivity, which leads to its high efficiency." It turns out unusual atomic vibrations help prevent "heat leaks," maximizing the conversion into electricity.
DOE's Office of Science, which advances materials for energy technologies, sponsored the study, which was led by an MIT-led Energy Frontier Research Center. The researchers used three DOE Office of Science User Facilities at ORNL--the Spallation Neutron Source, High Flux Isotope Reactor and Oak Ridge Leadership Computing Facility.
Through the Seebeck effect, thermoelectric devices produce a voltage and generate electric current when a temperature differential is maintained. Or, when powered with an external electricity source, the devices can actively pump the heat out for refrigeration applications.
To preserve a usable temperature gradient, thermoelectric materials need to be good conductors of electricity but bad conductors of heat. In 2014 researchers at Northwestern University discovered that tin selenide, which is inexpensive, could be the world's most efficient thermoelectric material.
The ORNL researchers observed atomic vibrations that underpin heat flow--called phonons--and tried to understand their origins in terms of electronic structure and chemistry.
"What we found is that this particular phonon mode is the one that's unstable, that 'freezes,'" Delaire said. "If you cool down the material, it goes from undistorted to distorted, and when you heat it up the distortion goes away. That is the atomic mechanism behind the freezing in of this particular phonon mode."
Knowledge the team gained may aid efforts to control thermal transport in a wide range of energy-related technologies, including thermal barrier coatings, nuclear fuels and high-power electronics.
The key to tin selenide's high efficiency was revealed through exploring the dynamics of atoms in the crystal lattice. In a harmonic system, waves of atomic vibrations can propagate freely. Many waves, carrying a lot of heat, can travel through the material without sensing each other. In an anharmonic system, in contrast, atomic vibration waves feel a viscous friction against each other. The friction creates a sort of slush that prevents heat propagation, much like the vibration dampers in a vehicle's shock absorbers. Tin selenide at the temperatures tested was strongly anharmonic: The phonon waves were strongly damped and the heat was well contained, so the temperature gradient could be preserved.
Co-lead author Jiawang Hong, a postdoctoral fellow working with Delaire, ran quantum dynamics simulations at the OLCF using Eos, a Cray XC30 supercomputer. The simulations of phonon dispersions, when plugged into software developed by the team, showed good agreement with the neutron scattering measurements taken at the SNS and HFIR by co-lead author Chen Li, also a postdoctoral fellow on Delaire's team. The paper's other authors were Andrew May and Dipanshu Bansal of ORNL's Materials Science and Technology Division and Songxue Chi, Tao Hong and Georg Ehlers of ORNL's Quantum Condensed Matter Division.
"With simulations we showed the strong underlying anharmonicity stems from a bonding instability," Delaire said. Below a phase transition of 810 kelvin (about 540 degrees C or 1000 degrees F), electronic orbitals spontaneously reorganize and the lattice assumes an accordion structure. Phonons feel this instability, which damps the oscillations--making tin selenide an outstanding thermoelectric material.
Fuller understanding of the fundamental principles that underpin useful properties could enable "materials by design." "Out of all the energy that goes into the U.S. economy every year, 60 percent is lost in the form of waste heat," Delaire said. "If you can recapture even a small fraction, you can have a big impact."
Improving energy sustainability
Thermoelectric materials can support sustainable energy. The MIT-led EFRC, with Oak Ridge and Brookhaven National Laboratories, Boston College and the University of Houston, has demonstrated that thermoelectric materials can be placed under solar panels, where a temperature difference can generate electricity cheaply.
Photovoltaic panels can be expensive, and many are needed to generate useful amounts of electricity. "With thermoelectric materials, once you have the temperature differential, you only need a comparatively small amount of material to produce the electricity," Delaire said. "In thermoelectric devices, energy conversion is really a direct link because the material does all the work. There are no moving parts. It generates the voltage from a temperature gradient. So understanding and optimizing the materials is key."
Thermoelectric materials still need to reach higher efficiencies for widespread application, but recent discoveries like understanding the dynamics of tin selenide have achieved big steps in that direction. They have already been big successes in niches including very long-lasting space batteries developed by NASA and DOE.
"This technology is very reliable," Delaire said. "That's why thermoelectric materials still power NASA's Voyager spacecraft 30 years after its launch."
Source: Oak Ridge National Laboratory
Subscribe to a free copy of one of our daily
Nanowerk Newsletter Email Digests
with a compilation of all of the day's news.
If you liked this article, please give it a quick review on reddit or StumbleUpon. Thanks!
These articles might interest you as well: