Disappearing gold a boon for nanolattices

(Nanowerk News) When gold vanishes from a very important location, it usually means trouble. At the nanoscale, however, it could provide more knowledge about certain types of materials. A recent discovery that enables scientists to replace gold nanoparticles with dummy "spacers" has allowed scientists to create materials with never-before-seen structures, which may lead to new properties.
In a new study (see paper in Nature Nanotechnology: "Synthetically programmable nanoparticle superlattices using a hollow three-dimensional spacer approach"; free access), researchers led by Professor Chad A. Mirkin from Northwestern University used the high-intensity X-rays provided at beamline 5-ID of the Advanced Photon Source (APS) at the U.S. Department of Energy's Argonne National Laboratory to look at "nanoparticle superlattices"—well-ordered arrangements of tiny nanoscale spheres that can be manipulated to take on a number of different properties.
The lattice element at left incorporates a gold inorganic nanoparticle and is thus arrange in a body-centered cubic configuration, in which each of the eight vertex particles are bound to the central particle. By removing the gold nanoparticle and incorporating a “dummy” spacer particle instead, the lattice rearranges into a simple cubic structure.
Superlattices have several characteristics that make them especially appealing to materials scientists, said Northwestern graduate student Evelyn Auyeung, one of the lead authors of the study. "Superlattices are defined by the fact that they maintain a well-organized structure over relatively long distances," she said. "The advantage to an ordered structure is that it gives you a better opportunity to tune or program the characteristics of the material."
In previous experiments conducted at Argonne, scientists examined the effect of using DNA as a kind of glue to reinforce the lattice structure. It had been shown that DNA is a versatile tool that directs nanoparticles into a variety of one-, two-, and three-dimensional superlattices, where the lattice parameter and symmetries depended on the length of the DNA, as well as the size and shapes of the particles used.
By incorporating the spacer particle—one that had no inorganic core—in place of the gold nanoparticle, the researchers were able to transform the structure of a body-centered cubic lattice to a simple cubic lattice. They extended this technique to other binary lattices and were able to synthesize many exotic lattices, including one which has no natural or synthetic equivalent for any known material. "Using these dummy particles gives us access to an entirely new design space," Auyeung said. "The next step is to study the kind of properties that these lattices have thanks to the different arrangement of the nanoparticles. If we can fully investigate this design space, we might be able to access some new emergent properties from these materials."
The work was supported by the U.S. Department of Energy's Basic Energy Sciences program.
The Advanced Photon Source at Argonne National Laboratory is one of four synchrotron radiation light sources supported by the U.S. Department of Energy's Office of Science. The APS is the source of the Western Hemisphere's brightest x-ray beams for research in virtually every scientific discipline. More than 3,500 researchers representing universities, industry, and academic institutions from every U.S. state visit the APS each year to carry out both applied and basic research in support of the BES mission.
Source: By Jared Sagoff, Argonne National Laboratory
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