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Posted: July 29, 2008

Scientists determine strength of 'liquid smoke'

(Nanowerk News) Researchers have created a 3D image of a material referred to as "liquid smoke."
Aerogel, also known as liquid smoke or "San Francisco fog," is an open-cell polymer with pores smaller than 50 nanometers in diameter.
For the first time, Lawrence Livermore and Lawrence Berkeley scientists have peered into this material and created three-dimensional images to determine its strength and potential new applications.
Scientists determine strength of 'liquid smoke'
A visible light laser beam incident from the left is focused onto the sample and acts as the excitation pulse. A 10 femtosecond soft X-ray pulse from the FEL is focused to a spot in the same location as the visible light laser. The X-ray pulse diffracts from the sample, carring informaiton about the sample structure to the CCD detector. (Lawrence Livermore National Laboratory)
Aerogel is a form of nanofoam, an engineered material designed for high strengh-to-weight ratio. Such nanofoam structires are also present in the fields of geology, phospholipids, cells, bone structure, polymers and structural materials, wherever lightness and strength are needed.
These mesoporous (2-50 nanometer-sized pores) crystalline materials can be used as catalysts for cleaner fuels and for the diffusion of water and oil in porous rocks. The structure and diffusion properties of nanofoams are determined by their structure.
Aerogels have the highest internal surface area per gram of material of any known materials because of its complicated, cross-linked internal structure. They also exhibit the best electrical, thermal and sound insulation properties of any known solid. It's not easy to see inside aerogel to determine the topology and structure at nanoscale-length scales because the smallest pore is normally too small to be observed internally by any conventional microscope.
But Livermore scientist Anton Barty and Lawrence Berkeley researcher and former LLNL scientist Stefano Marchesini were determined. They inverted coherent X-ray diffraction patterns to capture the three-dimensional bulk lattice arrangement of a micron-sized piece of aerogel.
"By imaging an isolated object at high resolution in three dimensions, we've opened the door to a range of applications in material science, nanotechnology and cellular biology," Barty said.
For about 20 years, Livermore has developed and improved aerogels for national security applications, synthesized electrically conductive inorganic aerogels for use as supercapacitors, and as a water purifier for extracting harmful contaminants from industrial waste or for desalinizing seawater, and even used aerogel to capture stardust particles during NASA's Stardust mission.
The new research shows that the lattice structure within aerogel is weaker than expected. The researchers saw a structure made up of nodes connected by thin beams.
"This blob and beam structure explains why these low-density materials are weaker than predicted and explains the high mass scaling exponent seen in the materials," Barty said.
In the future, the 3D analysis could be applied to other porous materials and could help modeling filtration problems such as oil and water in minerals, Barty said.
Other Livermore researchers include Aleksandr Noy, Stefan Hau-Riege, Alexander Artyukhin, Ted Baumann, James Stolken, Tony van Buuren, John Kinney and former LLNL researcher Henry Chapman, who is now at the Centre for Free Electron Laser Science, DESY, in Hamburg, Germany.
The team used the Advanced Photon Source at Argonne National Laboratory for the experiments.
The research appears in the July 29 issue of the journal Physical Review Letters.
Source: Lawrence Livermore National Laboratory
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