Posted: Oct 14, 2014 |
Beyond LEDs: Brighter, new energy-saving flat panel lights based on carbon nanotubes
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(Nanowerk News) Even as the 2014 Nobel Prize in Physics has enshrined light emitting diodes (LEDs) as the single most significant and disruptive energy-efficient lighting solution of today, scientists around the world continue unabated to search for the even-better-bulbs of tomorrow.
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Enter carbon electronics.
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Electronics based on carbon, especially carbon nanotubes (CNTs), are emerging as successors to silicon for making semiconductor materials. And they may enable a new generation of brighter, low-power, low-cost lighting devices that could challenge the dominance of light-emitting diodes (LEDs) in the future and help meet society's ever-escalating demand for greener bulbs.
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Scientists from Tohoku University in Japan have developed a new type of energy-efficient flat light source based on carbon nanotubes with very low power consumption of around 0.1 Watt for every hour's operation--about a hundred times lower than that of an LED.
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In the journal Review of Scientific Instruments ("Plannar light source using a phosphor screen with single-walled carbon nanotubes as field emitters"), the researchers detail the fabrication and optimization of the device, which is based on a phosphor screen and single-walled carbon nanotubes as electrodes in a diode structure. You can think of it as a field of tungsten filaments shrunk to microscopic proportions.
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This image shows a planar light source device from the front. (Image: N.Shimoi/Tohoku University)
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They assembled the device from a mixture liquid containing highly crystalline single-walled carbon nanotubes dispersed in an organic solvent mixed with a soap-like chemical known as a surfactant. Then, they "painted" the mixture onto the positive electrode or cathode, and scratched the surface with sandpaper to form a light panel capable of producing a large, stable and homogenous emission current with low energy consumption.
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"Our simple 'diode' panel could obtain high brightness efficiency of 60 Lumen per Watt, which holds excellent potential for a lighting device with low power consumption," said Norihiro Shimoi, the lead researcher and an associate professor of environmental studies at the Tohoku University.
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Brightness efficiency tells people how much light is being produced by a lighting source when consuming a unit amount of electric power, which is an important index to compare the energy-efficiency of different lighting devices, Shimoi said. For instance, LEDs can produce 100s Lumen per Watt and OLEDs (organic LEDs) around 40.
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Although the device has a diode-like structure, its light-emitting system is not based on a diode system, which are made from layers of semiconductors, materials that act like a cross between a conductor and an insulator, the electrical properties of which can be controlled with the addition of impurities called dopants.
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The new devices have luminescence systems that function more like cathode ray tubes, with carbon nanotubes acting as cathodes, and a phosphor screen in a vacuum cavity acting as the anode. Under a strong electric field, the cathode emits tight, high-speed beams of electrons through its sharp nanotube tips -- a phenomenon called field emission. The electrons then fly through the vacuum in the cavity, and hit the phosphor screen into glowing.
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"We have found that a cathode with highly crystalline single-walled carbon nanotubes and an anode with the improved phosphor screen in our diode structure obtained no flicker field emission current and good brightness homogeneity," Shimoi said.
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Field emission electron sources catch scientists' attention due to its ability to provide intense electron beams that are about a thousand times denser than conventional thermionic cathode (like filaments in an incandescent light bulb). That means field emission sources require much less power to operate and produce a much more directional and easily controllable stream of electrons.
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In recent years, carbon nanotubes have emerged as a promising material of electron field emitters, owing to their nano-scale needle shape and extraordinary properties of chemical stability, thermal conductivity and mechanical strength.
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Highly crystalline single-walled carbon nanotubes (HCSWCNT) have nearly zero defects in the carbon network on the surface, Shimoi explained. "The resistance of cathode electrode with highly crystalline single-walled carbon nanotube is very low. Thus, the new flat-panel device has smaller energy loss compared with other current lighting devices, which can be used to make energy-efficient cathodes that with low power consumption."
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"Many researchers have attempted to construct light sources with carbon nanotubes as field emitter," Shimoi said. "But nobody has developed an equivalent and simpler lighting device."
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Considering the major step for device manufacture--the wet coating process is a low-cost but stable process to fabricate large-area and uniformly thin films, the flat-plane emission device has the potential to provide a new approach to lighting in people's life style and reduce carbon dioxide emissions on the earth, Shimoi said.
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