| Nov 12, 2021 |
3D chemistry boosts perovskite efficiency to 23.9%
(Nanowerk News) Perovskites are hybrid compounds made from metal halides and organic constituents, and show great potential in a range of applications, e.g. LED lights, lasers, and photodetectors. However, their major contribution is in solar cells, where they are poised to overtake the market and replace their silicon counterparts.
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Among the leading candidates for highly efficient and stable solar cells are lead iodide perovskites, which show excellent light-harvesting capabilities. However, their efficiency depends greatly on their manufacturing, and a key factor is removing defects from their light-harvesting surface.
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Passivation and perovskite efficiency
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The way this is typically done is with a method called “passivation”, which coats the surface of perovskite films with chemicals (alkylammonium halides) to make them more resistant and stable. The process adds a two-dimensional perovskite layer on top of the primary perovskite light absorber, which improves the stability of the device.
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The problem is that passivation actually backfires by forming so-called “in-plane” perovskite layers that don’t “move” electrical charge as well, especially under heat. This is an obvious disadvantage for scaling up and commercializing potential solar panels.
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3D chemistry to the rescue
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In a new study (Nature Communications, "Tuning structural isomers of phenylenediammonium to afford efficient and stable perovskite solar cells and modules"), scientists led by Mohammad Nazeeruddin at EPFL’s School of Basic Sciences, have found a way to solve the problem by treating them with different isomers of an iodide used to make perovskites. In chemistry, isomers are compounds that have the same molecular formulas but their atoms are arranged differently in three-dimensional space.
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The scientists studied the minimum energy required to form two-dimensional perovskites from different isomers of the iodide PDEAI2 (phenylenediethylammonium). The isomers were designed for what the researchers call “tailored defect passivation”, meaning that their passivation effect on perovskites was very well characterized in advance.
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| Fig. 1 a The structures of the PDEAI2 isomers. b J-V characteristics of the champion device with o-PDEAI2. c Photograph of the fabricated perovskite solar module. (Image: MK Nazeeruddin) (click on image to enlarge)
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The approach turned out to be very effective in staving off the negative effects of passivation on perovskite efficiency. Specifically, the most effective PDEAI2 isomer was also the most “sterically hindered”, a term that refers to a slowing of chemical reactivity simply because of the compound’s molecular bulk. In fact, steric hindrance is often used to prevent or minimize unwanted reactions.
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The perovskite solar cells produced with this method showed an efficiency of 23.9% with operational stability beyond 1000 hours. The work also achieved a record efficiency of 21.4% for perovskite modules with an active area of 26 cm2.
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