Showing Spotlights 9 - 16 of 20 in category Nanofiltration (newest first):
One of the problems in modern separation science and technology is the challenge of separating gaseous mixtures that consist of very similar particles, for example, hydrogen isotope mixtures; mixtures of noble gases; etc. The problem arises because small particles such as hydrogen isotopes share similar size and shape (only their molecular mass is different). While this problem can be technically solved, currently available separation methods such as thermal diffusion, cryogenic distillation, and centrifugation, tend to be time and energy intensive. New theoretical work now shows that narrow carbon nanotubes (CNTs) seem to be an attractive alternative. By using CNTs as nanoporous molecular sieves, the separation of parahydrogen molecules from mixtures of classical particles at cryogenic temperatures seems to be possible.
Apr 14th, 2011
One possible option for reducing CO2 emissions from power plants is to capture them before they hit the atmosphere and store the gas underground. This technique is called Carbon dioxide Capture and Storage. However, before CO2 can be stored, it must be separated from the other waste gases resulting from combustion or industrial processes. Most current methods used for this type of filtration are expensive and require the use of chemicals. Nanotechnology techniques to fabricate nanoscale thin membranes could lead to new membrane technology that could change that.
Current membranes are in many cases not competitive for large scale applications, because their permeance for carbon dioxide is not high enough. Researchers in Germany have now reported the development and manufacturing of nanometric thin film membranes with record performance.
Sep 21st, 2010
Various nanotechnologies are being researched for applications in water treatment because the removal of bacteria and other organisms from water is an extremely important process, not only for drinking and sanitation but also industrially as biofouling is a commonplace and serious problem. In what could be developed as a a cheap point-of-use water filter for deactivating pathogens in water, or as a new component to be integrated into existing filtration systems to kill microorganisms which cause biofouling in downstream filters, researchers have now demonstrated a textile based device for the high speed electrical sterilization of water. They came up with a new strategy for taking advantage of silver nanowires' and carbon nanotubes' unique ability to form complex multiscale coatings on cotton to produce an electrically conducting and high surface area device for the active, high-throughput inactivation of bacteria in water.
Aug 26th, 2010
Delivering healthy proteins directly into human cells to replace malfunctioning proteins is considered one of the most direct and safe approaches for treating diseases. Controlled and long-term protein drug delivery has also been considered as one of the most promising biomedical applications of nanotechnology. So far, though, the effectiveness of protein therapy has been limited by low delivery efficiency and the poor stability of proteins, which are frequently broken down and digested by cells' protease enzymes before they reach their intended target. This not only makes the drugs ineffective, it can also cause unpredictable side effects such as inflammation, toxicity, and immune responses. The best way for the delivery of protein drugs without denaturation might be possible by exploiting the passive diffusion through a membrane without physical and chemical stresses. This can be achieved when pore sizes in a membrane are controlled to satisfy the single-file diffusion condition of protein drugs.
Aug 10th, 2010
Ultrathin nanosieves with a thickness smaller than the size of the pores are especially advantageous for applications in materials separation since they result in an increase of flow across the nanosieve. Separation of complex biological fluids can particularly benefit from novel, chemically functionalized nanosieves, since many bioanalytical problems in proteomics or medical diagnostics cannot be solved with conventional separation technologies. Researchers in Germany have now fabricated chemically functionalized nanosieves with a thickness of only 1 nm - the thinnest free-standing nanosieve membranes that have been reported so far. The size of the nanoholes in the membranes can be flexibly adjusted down to 30 nm by choosing appropriate conditions for lithography.
Dec 9th, 2009
Advanced material engineering techniques can structure surfaces that allow dynamic tuning of their wettability all the way from superhydrophobic (i.e. repelling) behavior to almost complete wetting (i.e. superhydrophilic or strongly absorbing) - but these surfaces only work with high-surface-tension liquids. Almost all organic liquids that are ubiquitous in human environment such as oils, solvents, detergents, etc. have fairly low surface tensions and thus readily wet even superhydrophobic surfaces. In a previous Spotlight we reported how researchers have been creating surfaces that would extend superhydrophobic behavior to all liquids, no matter what the surface tension. New work coming out of MIT now describes a novel nanostructures membrane that can be switched between superhydrophilic and superhydrophobic behavior on demand. Think of it as an 'oil spill clean-up paper towel' that absorbs only the oil but not the water. Given the global scale of severe water pollution arising from oil spills and industrial organic pollutants, this nanomaterial may prove particularly useful in the design of recyclable absorbents with significant environmental impact.
May 30th, 2008
Separation and purification of bio-molecules such as proteins and viruses are important processes in the biotechnology industry. The risk of contamination with either known or unknown viruses in biological or therapeutic products require production processes that - ideally - completely eliminate the risks of virus contamination. Since the existence of very small amounts of viruses with a size of tens of nanometers causes severe damage to the entire bio-process, the filtration of viruses has to be pretty much perfect. Micro- and ultrafiltration have been successfully used in numerous processes as a robust step for virus reduction but they are not 100% effective. Currently used ultrafiltration membranes still allow smaller-sized virus particles to permeate into a small number of abnormally large-sized pores in the membrane. This broad size distribution of pores in ultrafiltration membranes and the low density of pores in track-etched membranes limit the practical use of virus filtration.
May 23rd, 2008
Nanopores function as membrane channels in all living systems, where they serve as sensitive electro-mechanical devices that regulate electrical potential, ionic flow, and molecular transport through the cell membrane. Scientists are studying nanopore construction with the goal of making man-made cell membranes and single molecule detectors. So far, nanoporous membrane-based separations simply use the difference in size of the analytes relative to pore size in the membrane. Here, for a nanopore to be useful as a single molecule detector, its diameter must not be much larger than the size of the molecule to be detected. When a single molecule enters a nanopore in an insulating membrane, it causes changes in the nanopore's electrical properties, which then can be detected and measured. In order to bring about selectivity beyond size, it is necessary that methods for functionalizing the membrane pores are available. To that end, researchers have developed a very simple, but versatile, method for decorating the nanoporous membranes with functional groups. By uniformly modifying the internal cavities of nanopores with various polymers they were able to demonstrate selectivities based on size, charge and hydrophobicity of the molecule passing through the nanopore.
Feb 6th, 2008