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Posted: Nov 30, 2016
Tailor-made membranes for the environment
(Nanowerk News) In technical systems, membranes can be used to separate gases - in a manner that is more efficient and cost-effective than with established methods. Membrane systems thus enable the separation of harmful greenhouse gases with comparatively low losses.
At the same time, they also make it possible to obtain high-purity hydrogen for clean energy generation and storage, making ceramic membranes a key technology for transforming the energy sector (Energiewende).
One option for separating hydrogen from gas mixtures is a two-phase membrane. "This consists of two ceramic materials. The individual grains are only a thousandth of a millimetre in size and exhibit both ionic and electronic conductivity," explains Dr. Mariya Ivanova from the Juelich Institute of Energy and Climate Research.
The components of the hydrogen - protons and electrons - are thus transported individually through the membrane. On the other side, they combine to form high-purity hydrogen. This is made possible by tailor-made vacancies in the crystal lattice of the ceramics, which are occupied by protons. These protons, driven by pressure differences and temperature, are conducted through the material of the membrane.
This is a transmission electron microscope image of the membrane, provided by the Ernst Ruska-Centre. The two phases for proton and electron conduction are marked in color: barium cerate doped with europium oxide (BCEO) and cerium doped with yttrium and europium oxide (CYO). (Image: Forschungszentrum Jülich)
"They dock onto a hydrogen ion and jump in the direction of the lower pressure to the next hydrogen ion, from vacancy to vacancy, until they form elementary hydrogen again on the other side," says Mariya Ivanova. "The electrons are transported through the second component of the ceramic and ensure that charge equalization occurs."
However, the method still has a number of weak points. For example, high temperatures are needed for hydrogen separation, thus meaning it requires a lot of energy. In addition, the membranes investigated so far are not stable and become unusable in a carbonaceous environment. The hydrogen flow rate is also not yet high enough.
"It is nearly twice as high as in all other cases that have been documented to date," says a delighted Ivanova.
The Juelich membranes used for the measurements are only the size of a 10 cent coin and half a millimetre thick. "It is still too early to be thinking about an industrial application," explains Ivanova. "We will continue to conduct research, searching for a suitable material with a high flow rate and stability as well as low costs. The next step will be to increase component size to make it fit for industrial application." The researchers are initially aiming to achieve an area of ten by ten square centimetres.