Due to their exceptional electronic and mechanical properties, as well as their nanoscale size, carbon nanotubes (CNTs) could become the active electronic elements in addressing next generation electronic requirements for which silicon is not a solution. Already, it has been shown extensively that semiconducting CNTs can be made into electronic components such as transistors and switches. Their thermal, mechanical, chemical stability, and large current-carrying capacity make CNTs attractive for applications not only in in electrical interconnects but also field-effect transistors, cold cathode field emitters, and sensors. Some of the problems in developing CNT-based electronic devices have to do with building reliable interconnections between CNTs and external electrical and mechanical systems and in developing a reliable fabrication batch process to allow for industrial-scale mass production that supports the direct manipulation and placement/growth of CNTs at specific locations. Pointing to a possible solution, researchers now have demonstrated controllable and simultaneous wafer-scale assembly of CNT networks by dielectrophoresis.
DNA, the blueprint of life, and electronics seem to be two completely different things but it appears that DNA could offer a solution to many of the hurdles that need to be overcome in further scaling down electronic circuits beyond a certain point. The reason why DNA could be useful in nanotechnology for the design of electric circuits is the fact that it actually is the best nanowire in existence - it self-assembles, it self-replicates and it can adopt various states and conformations. Not surprisingly, performing reliable experiments on a single oligo-DNA molecule is an extremely delicate task as partly contradicting research reports demonstrate: Different DNA transport experiments have shown that DNA may be insulating, semiconducting, or metallic. Among the numerous factors that could impact the results are the quality of the DNA-electrode interface, the base pair, the charge injection into the molecule, or environmental effects such as humidity or temperature. Researchers have now demonstrated a novel carbon nanotube-based nanoelectronic platform as proof of concept that single DNA molecules can be detected. This novel detection technique is based on change in electrical conductance upon selective hybridization of the complementary target DNA with the single stranded probe attached to the system. The single-stranded sequence-specific probe DNA whose ends are modified with amine is attached between two carbon nanotubes/nanowires using dielectrophoresis (DEP). This platform can be used for understanding how electrical charge moves through DNA which could help researchers understand and perhaps develop a technique for reversing the damage of DNA done by oxidation and mutation.
As a critical component of optoelectronic devices, transparent conductive coatings pervade modern technology. The most widely used standard coating is indium tin oxide (ITO), used in nearly all flat panel displays and microdisplays. Causing problems for manufacturers, though, Indium is expensive and scarce and demand is increasing. From the depressed levels of $60/kg in 2002, indium prices rose to over $1,000/kg during the summer of this year. Recently, prices have fallen back to between $400-$500/kg. But, geologists say the cost of indium may not matter soon, because the earth's supply of this element could be gone within just a few years. In addition to the limited availability of Indium there are other reasons that make ITO and other metal oxides such as FTO (fluorine tin oxide) increasingly problematic for electronics manufacturers: the instability of these metal oxides in the presence of acid or base; their susceptibility to ion diffusion into polymer layers; their limited transparency in the near-infrared region; and lastly, the current leakage of FTO devices caused by FTO structure defects. This has made the search for novel transparent electrode materials with good stability, high transparency and excellent conductivity a crucial goal for optoelectronic researchers. Recent work by researchers in Germany exploits ultra-thin transparent conductive graphene films as window electrodes in solar cells.
We have written plenty of Spotlights so far on carbon nanotubes and nanoelectronics. For instance, carbon nanotube (CNT) transistors have the potential to outperform state-of-the-art silicon devices. Researchers around the world have been working for years on advances at the device level, things like switches and wires and optimizing individual CNT transistors. More recently, scientists have begun to integrate nanotechnology-based materials and devices into larger systems - a crucial step in getting nanotechnology from the lab to the fab. Last year, for instance IBM reported to have built the first complete electronic integrated circuit around a single carbon nanotube (An integrated logic circuit assembled on a single carbon nanotube). Researchers in California have now reported another step towards showing nanoelectronics in systems: They have developed the world's first working radio system that receives radio waves wirelessly and converts them to sound signals through a nano-sized detector made of CNTs. Although this is only the demonstration of a single critical component (the CNT as demodulator) of an entire radio system, it is entirely possible that at some point in the future all components of a working radio could be nanoscale, thus allowing a truly nanoscale wireless communications system (apart from the magnitude of the technological achievement, this is probably great news for surveillance freaks, not so much for privacy advocates).
Nanoelectronics deals with functional electron devices, such as transistors, in the nanoscale range size. As the name implies, nanoelectronics runs on electricity, i.e. the transport of electrons. Another approach to creating faster,smaller and more energy-efficient electronics is to move the field of optical information processing towards the nanoscale. Optical nanoelectronics will work with light instead of electron transport. Here the usual circuit elements such as inductors, capacitors and resistors could be created in order to operate using infrared or visible light. Using nanotechnology, researchers are able to create structures that could operate on the same or smaller scale as the wavelength of light (the wavelength of visible light is roughly between 400 and 700 nanometers). Going beyond 'conventional' nanoelectronics, researchers have now proposed a form of optical circuitry in which a network of subwavelength nanoscale metamaterial structures and nanoparticles may provide a mechanism for tailoring, patterning, and manipulating optical electric fields in a subwavelength domain, leading to the possibility of optical information processing at the nanometer scale.
Yesterday we wrote about air bridges in nanotechnology fabrication. Today we show a practical example. Traditionally, electronic devices have been fabricated by top-down fabrication methods. Conducting polymers, for instance, have been synthesized as micro- and nanoscale fibers, tubes and wires for more than 10 years now. More recently, nanowires have been integrated into electronic circuits, making possible the development of devices such as polymer nanowire chemical sensors with superior performance. What most of these fabrication techniques have in common is that they are template-based (e.g. lithography or DNA templates) or depend on specialized fiber forming techniques such as electrospinning. However, as electronic components become smaller and smaller it is increasingly more difficult to use existing methods of fabrication. New methods must be developed. A group of researchers in Australia have demonstrated a technique for growing ordered polymer nanowires within a pre-patterned electronic circuit such that electrical contacts to the nanowires are made in situ during the growth procedure, avoiding the time-consuming and challenging task of manipulating nanowires into position and making electrical contacts post-synthesis.
Transistors are the fundamental building blocks of our everyday modern electronics; they are the tiny switches that process the ones and zeroes that make up our digital world. Transistors control the flow of electricity by switching current on or off and by amplifying electrical signals in the circuitry that governs the operation of our computers, cellular phones, iPods and any other electronic device you can think of. The first transistor used in commercial applications was in the Regency TR-1 transistor radio, which went on sale in 1954 for $49.95, that's over $375 in today's dollars (for everyone in the iPod generation - watch this fascinating 1955 video clip artifact how the first transistor radio was hand built). While the first transistors were over 1 centimeter in diameter, the smallest transistors today are just 30 nanometers thick - three million times smaller. This feat would be equivalent to shrinking the 509-meter tall Taipei 101 Tower, currently the tallest building in the world, to the size of a 1.6 millimeter tall grain of rice. The 32nm microprocessor Intel plans to introduce in 2009 will pack a whopping 1.9 billion transistors. However, current microprocessor technology is quickly approaching a physical barrier. Switching the current by raising and lowering the electron energy barrier generates heat, which becomes a huge problem as device densities approach the atomic limit. An intriguing - and technologically daunting - alternative would be to exploit the wave nature of the electron, rather than its particle properties, to control current flow on the nanoscale. Such a device, called the Quantum Interference Effect Transistor (QuIET), has been proposed by researchers in Arizona. This device could be as small as a single benzene molecule, and would produce much less heat than a conventional field effect transistor.
Lithium-ion (Li-ion) batteries are a type of rechargeable battery commonly used in consumer electronics. They are currently one of the most popular types of battery for portable electronics, with one of the best capacity-to-weight ratios, no memory effect, and a slow loss of charge when not in use. Lithium is useful in batteries because of its lightness (it is the lightest metal) and because of the high voltage of the redox reaction between Li and Li+. In lithium ion batteries, a layered compound - lithium copper oxide or or lithium nickel oxide - is utilized as a cathode. Although this material can provide high capacity, its charging/discharging rates are slow because these processes include the absorption/desorption of lithium in the cathode. Recently, organic radical batteries have been developed as a new type of rechargeable battery, in which organic radical polymers are utilized as a cathode active material. They achieved a very fast chargeable/dischargeable rate, though their capacities are lower than those of the lithium ion batteries. A lot of research has gone into fabricating lithium batteries that achieve both high capacity and fast charging/discharging. Researchers in Japan came up with a completely new idea - the molecular cluster battery - where the cathode active material is a well-known manganese molecular cluster that is stable and insoluble to most solvents and exhibits a multi-step redox reaction. Although the battery was rechargeable, in early experiments the fast charging–discharging was not yet achieved due to the chemical decomposition of the cluster. Nevertheless, this is a first step that opens up a new branch of research into high-performance rechargeable molecular cluster batteries.