Before the superior electronic properties of graphene can be utilized in industrial products, researchers must find a way that allows the mass production of graphene-based devices. New work by a European research team now demonstrates the feasibility of graphene synthesis on commercially available cubic SiC/Si substrates of 300 mm and greater in diameter, which result in graphene flakes electronically decoupled from the substrate. This work demonstrates that it is possible to grow high-quality graphene layers on beta-SiC(001), i.e. on the cubic modification of this material. This is a very important step, since beta-SiC is commercially available and it can be well integrated into present electronic production processes.
Among the various production methods for carbon nanotubes and graphene, currently only chemical vapor deposition techniques demonstrate a significant opportunity for mass production of CNT material. Using the CVD process, which is based on the catalytic action of metals, manufacturers can combine a metal catalyst such as iron with reaction gases such as hydrogen to form carbon nanotubes inside a high-temperature furnace. In order to optimize the synthesis process, a detailed understanding of the interaction between nanotubes or graphene and metal atoms is required - something that has been missing so far. Researchers in France have now shown that it is possible to create atomic-scale defects in carbon nanotubes and in graphene in preselected positions with a focused electron beam and to use these defects as trapping centers for foreign atoms.
Graphite oxide sheet, now being named graphene oxide - a compound of carbon, oxygen, and hydrogen obtained by treating graphite with strong oxidizers - has attracted substantial interest as a possible intermediate for the manufacture of graphene. It has been largely viewed as hydrophilic - having a strong affinity for water illustrated by its excellent colloidal stability in water. In what should help to better understand and improve the solution processing of graphite oxide-based graphene materials and open up opportunities to design new functional graphite oxide-based hybrid materials, researchers have now reported that graphite oxide is amphiphilic - possessing both hydrophilic and lipophilic (fat-liking) properties - and can adsorb onto air-water, oil-water and solid-water interfaces.
As it is becoming clearer that one of the critical issues for developing functional nanomachines is the generation of energy required to power them, research into developing nanoscale energy sources has been picking up substantially. The energy to be fed into a nanogenerator is likely to be mechanical energy that is converted into electric energy that then will be used to power nanodevices without using a battery. With the emergence of nanotechnology and the use of nanomaterials, the field of piezoelectrics and nanopiezotronics has experienced a lot of new and interesting research efforts. Researchers in Korea have now demonstrated the first use of chemical vapor deposition-grown large-scale graphene sheets as transparent electrodes for fully transparent and flexible nanogenerators.
Silicon has dominated solid-state electronics for more than four decades but now a variety of other materials are being explored in photonic devices to expand the wavelength range of operation and to improve performance. Graphene is such a material - although most research on graphene so far has focused mainly on electronics. IBM researchers have now shown that graphene-based devices can be used in optical communications. Introducing this new material system into photonics could have a significant impact on mainstream optical applications. By using graphene, researchers make use of the internal electric field that exists at the interface of graphene and metal. Through a sophisticated combination of palladium and titanium electrodes they created a photodetector that does not rely on external current.
Carbon-supported catalysts are widely used in many applications. For example, platinum nanoparticles supported on bulk carbon frameworks are used as fuel cell electrodes. The obvious challenge is to have a large area of carbon surface so that the catalyst particles can be dispersed without any aggregation. Graphene with its 2D nanostructure provides a large surface area (theoretically, the surface area of graphene is about 2600 square meters per gram) to anchor catalyst particles. Scientists have now succeeded in dispersing two different types of nanoparticles - silver and titanium dioxide - on a reduced graphene oxide at different sites without any aggregation.
A group of researchers from Singapore, led by Professor Dingyuan Tang from Nanyang Technological University and Professor Kian Ping Loh from National University of Singapore, have reported the first breakthrough in using few-layer graphene as a saturable absorber for the mode locking of lasers. Despite its prominent mechanical and electrical properties, graphene's optical response has previously been considered to be weak and featureless, so the main interests of the research community are centered on its electronics properties. But now, Tang and Loh demonstrate that graphene can be used for telecommunications applications and that its weak and universal optical response might be turned into advantages for ultrafast photonics applications.
Graphene based sheets such as pristine graphene, graphene oxide, or reduced graphene oxide are basically single atomic layers of carbon network. They are the world's thinnest materials. A general visualization method that allows quick observation of these sheets would be highly desirable as it can greatly facilitate sample evaluation and manipulation, and provide immediate feedback to improve synthesis and processing strategies. Current imaging techniques for observing graphene based sheets include atomic force microscopy, transmission electron microscopy, scanning electron microscopy and optical microscopy. Some of these techniques are rather low-throughput. And all the current techniques require the use of special types of substrates. This greatly limits the capability to study these materials. Researchers from Northwestern University have now reported a new method, namely fluorescence quenching microscopy, for visualizing graphene-based sheets.