As far as test tubes go, it doesn't get any smaller than a single-walled carbon nanotube (SWCNT). Among the wide range of interesting properties exhibited by SWCNTs is their capacity to encapsulate molecules within their quasi one-dimensional cavity. The confinement offered by the nanotube could serve as a nanoscale test tube to constrain a chemical reaction. This was demonstrated in principle back in 1998, when the coalescence of adjacent fullerenes was observed by transmission electron microscopy. In the following years, scientists have extensively experimented with filling nanotubes with other fullerenes, atoms, molecules and, very recently, with organic molecules. Owing to their large variety with diverse chemical properties, the incorporated organic molecules can tune the properties of the SWCNTs. Scientists are intrigued by the possibilities that SWCNTs' use as a reaction tube offers for chemistry at the nanoscale. Nanochemistry - a key to control self-assembly processes prerequisite for nanotechnology - in essence would produce stable chemical reactions inside a confined nanoscale space. Encapsulated inside this nanoscale space, molecules are isolated from the outside environment, which allows one to identify and control the source and incidence of chemical reactions. Recent work has demonstrated this new chemistry by using SWCNTs as a nanometer-scale reaction furnace.
Sophisticated molecular-size motors have evolved in nature, where they are used in virtually every important biological process. In contrast, the development of synthetic nanomotors that mimic the function of these amazing natural systems and could be used in man-made nanodevices is in its infancy. Building nanoscale motors is not just an exercise in scaling down the design of a macroworld engine to nanoscale dimensions. Many factors such as friction, heat dissipation and many other mechanical behaviors are just very different at this scale - everything is constantly moving (under kinetic energy supplied by the heat of the surroundings) and being buffeted by other atoms and molecules (Brownian motion). In nature, biological motors use catalytic reactions to create forces based on chemical changes. These motors do not require external energy sources such as electric or magnetic fields. Instead, the input energy is supplied locally and chemically. Despite impressive progress over the past years, man-made nanomachines lack the efficiency and speed of their biological counterparts. New research has demonstrated that the incorporation of carbon nanotubes (CNT) into the platinum component of asymmetric metal nanowire motors leads to dramatically accelerated movement in hydrogen peroxide solutions, with average speeds of 50-60 micrometers per second.
The race is on to develop the next generation of nanotechnology-enabled electrochemical energy storage devices, also knows as batteries. Lithium of course has long been recognized as an ideal material for energy storage due to its light weight and high electrochemical energy potential, as witnessed by the ubiquitous use of Li-ion batteries. There still seems to be considerable potential to further improve the performance characteristics of these Li-ion batteries. There have been many design approaches to creating lithium ion batteries but they usually share common features: The positive electrode is typically a lithium metal oxide, with various metals used such as cobalt, nickel, and manganese. The negative electrode is typically a carbon compound or natural or synthetic graphite. Researchers in Germany have now demonstrated a simple route for transforming cheap commercial carbon nanotubes into highly efficient carbon for electrochemical energy storage applications. When tested as electrode materials for lithium batteries, this composite material exhibits excellent performance over long test cycles.
The toxicity issues surrounding carbon nanotubes (CNTs) are highly relevant for two reasons: Firstly, as more and more products containing CNTs come to market, there is a chance that free CNTs get released during their life cycles, most likely during production or disposal, and find their way through the environment into the body. Secondly, and much more pertinent with regard to potential health risks, is the use of CNTs in biological and medical settings. CNTs interesting structural, chemical, electrical, and optical properties are explored by numerous research groups around the world with the goal of drastically improving performance and efficacy of biological detection, imaging, and therapy applications. In many of these envisaged applications, CNTs would be deliberately injected or implanted in the body. For instance, CNT-based intercellular molecular delivery vehicles have been developed for intracellular gene and drug delivery in vitro. What these CNTs do once inside the body and after they discharge their medical payloads is not well understood. Cell culture studies have shown evidence of cytotoxicity and oxidative stress induced by single-walled carbon nanotubes (SWCNTs), depending on whether and to what degree they are functionalized or oxidized. A new study at Stanford University tested non-covalently pegylated SWCNTs as a 'least toxic scenario', and oxidized, covalently functionalized nanotubes as a 'most toxic scenario' in a study on mice. It was found that SWCNTs injected intravenously into nude mice do not appear to have any significant toxicity during an observation period of four months following injection.
Safe, efficient and compact hydrogen storage is a major challenge in order to realize hydrogen powered transport. According to the U.S. Department of Energy's Freedom CAR program roadmap, the on-board hydrogen storage system should provide a gravimetric density of 6 wt% at room temperature to be considered for technological implementation. Currently, the storage of hydrogen in the absorbed form is considered as the most appropriate way to solve this problem. Research groups worldwide are seeking and experimenting with materials capable of absorbing and releasing large quantities of hydrogen easily, reliably, and safely. One candidate material that is being considered as a candidate for hydrogen storage media is single-walled carbon nanotubes. So far, carbon nanotubes have been unable to meet the DOE's hydrogen storage target. New theoretical work from China suggests that silicon nanotubes can store hydrogen more efficiently than their carbon nanotube counterparts. This raises the possibility that, after powering the micro-electronics revolution, silicon could also become a key material for the future hydrogen economy.
There are several touch sensor technologies available to power touch screens like the ones you can find on your bank ATM, airport check-in kiosk or other self-service terminals. What they all have in common is that they are sensitive to human touch because their screens are coated with a special transparent thin film that act as a sensor. This sensor generally has an electrical current or signal going through it and touching the screen causes a voltage or signal change. Apart from touch screens, transparent conductive thin films are used in numerous products such as flat-panel displays, solar cells or as thermal barriers in energy-saving windows. Future applications will include flexible displays for e-papers, smart cards, 'heads-up' displays integrated into cockpit and car windows, and windows that can be used as a light source at night. All this has driven increased research activity in finding alternative novel transparent electrode materials with good stability, high transparency and excellent conductivity. Graphene is one good candidate and films based on carbon nanotubes have attracted significant attention recently as well. Researchers now have demonstrated the use of metallic nanotubes to make thin films that are semitransparent, highly conductive, flexible and come in a variety of colors.
Self-assembly and self-organization are terms used to describe processes in which a disordered system of pre-existing components forms an organized structure or pattern as a consequence of specific, local interactions among the components themselves, without external direction. Self-organizing processes are common throughout nature and involve components from the molecular (e.g. protein folding) to the planetary scale (e.g. weather systems) and even beyond (e.g. galaxies). Self-assembly has become an especially important concept in nanotechnology. As miniaturization reaches the nanoscale, conventional manufacturing technologies fail because it has not been possible (yet) to build machinery that assembles nanoscale components into functional devices. Until robotic assemblers capable of nanofabrication can be built, self-assembly - together with chemical synthesis - will be the necessary technology to develop for bottom-up fabrication. The key to using self-assembly as a controlled and directed fabrication process lies in designing the components that are required to self-assemble into desired patterns and functions. Self-assembly reflects information coded - as shape, surface properties, charge, polarizability, magnetic dipole, mass, etc. - in individual components; these characteristics determine the interactions among them.
Despite their name, carbon nanotubes (CNTs) are not made of 100% carbon. Depending on which of the various synthesis techniques is used in their production, CNTs have variable chemistries and physical properties resulting from their different metal catalysts or amorphous carbon coatings. As a result, they may contain large percentages of metal and carbonaceous impurities which will have different environmental and toxicological impacts. In early toxicological studies, researchers obtained confounding results - in some studies nanotubes were toxic; in others, they were not. The apparent contradictions were actually a result of the materials that the researchers were using, not appreciating that 'carbon nanotubes' are really 'carbon nanotubes + metal + amorphous impurities'. Ignoring these impurities prohibits scientists from fully understanding the material's electronic character, environmental transport, transformation, and ecotoxicology. To address these needs, a group of researchers measured the elemental, molecular, and stable carbon isotope compositions of commercially available single-walled carbon nanotubes (SWCNTs) produced by ten companies in the United States, giving a true picture of their diversity and chemical complexity. This diversity and complexity is extremely important from both fate and toxicity perspectives.