To explore the intrinsic mechanisms of the electrochemical reactions of porous graphene oxide in situ, the single-nanowire electrochemical probe is an effective tool. Although graphene is usually used as an additive in active materials to improve the electrochemical performance, how graphene influences the electrochemical performance and reaction mechanisms of electrode materials is under dispute. To address these issues, researchers have explored single-nanowire electrochemical devices to investigate the capacitance, ion diffusion coefficient, and charge storage mechanisms of graphene.
Lithium (Li) metal-based batteries such as Li-sulfur and Li-air batteries have received considerable attention because Li metal can store 10 times more energy than graphite. However, there are safety and performance concerns for these types of batteries that arise from the formation of dendrites on the electrodes. To address this issue, researchers have proposed an unstacked graphene nanostructured lithium metal anode for lithium metal batteries to inhibit lithium dendrite growth and bring superior electrochemistry performance.
Capacity decay caused by polysulfides' detachment from the cathode framework has been a major issue preventing the broad application of lithium-sulfur (Li-S) batteries. Researchers discovered that it is the incompatibility between polar lithium polysulfide molecules and commonly used nanocarbon cathode scaffolds that restraines the redox reactivity. By incorporating sulfiphilic cobalt disulfide into carbon/sulfur cathodes, They managed to introduce strong interaction between lithium polysulfides and CoS2 under working conditions.
The two major problems with lithium-sulfur batteries stem from the intrinsic inert reaction kinetics of sulfur redox and the unique 'shuttle' mechanism described as that soluble intermediates - polysulfides consisting of lithium-terminated sulfur-chains - diffuse between the cathode and anode, thus being consumed within the battery instead of being utilized. To solve these issues and to improve battery performance relies on not only the electrode materials but also other cell components such as the separator.
A carbon material with high electrical conductivity, high specific surface area, tunable pore structure, mechanically robust framework, and high chemical stability is an important requirement for advanced electrochemical energy storage. However, neither porous carbon or sp2 carbon can full meet these requirements yet. How to create a conductive carbon material with especially large pore volume, and hence large surface area, has therefore been a key focus in electrode research.
Against the double-whammy backdrop of an energy challenge and a climate challenge it is the role of innovative energy technologies to provide socially acceptable solutions through energy savings; efficiency gains; and decarbonization. Nanotechnology It may not be the silver bullet, but nanomaterials and nanoscale applications will have an important role to play. This article provides an overview of the issues and nanomaterials and applications that are being researched in the field of energy.
Researchers have been looking to design catalyst materials that can significantly enhance the performance of oxygen evolution reaction (OER), a key eletrode reaction that is an enabling process for many energy storage options such as direct-solar and electricity-driven water splitting and rechargeable metal-air batteries. However, OER suffers from sluggish kinetics - but a novel material inspired by the pomegranate might change that.
Self-healing of a device is different from material self-healing because the devices contain electronic circuits. Self-healing of a device includes materials self-healing plus alignment of electrodes, which is very difficult but essential. Researchers have now come up with the idea of using magnetic force to assist alignment of electrodes in a circuit, facilitating self-healing of the whole device. To realize this idea, they designed and fabricated an electrically and mechanically self-healable yarn-based supercapacitor by wrapping magnetic electrodes with a self-healing carboxylated polyurethane shell.